trans-4-methyl-4'-(2-(4-octadecyloxyphenyl)vinyl)-2,2'-bipyridine | 378792-99-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: trans-4-methyl-4'-(2-(4-octadecyloxyphenyl)vinyl)-2,2'-bipyridine
• 英文别名: 2-(4-methylpyridin-2-yl)-4-[(E)-2-(4-octadecoxyphenyl)ethenyl]pyridine
• CAS: 378792-99-5
• 化学式: C₃₇H₅₂N₂O
• 分子量: 540.833
• InChiKey: MYITVXPJNCHFOJ-FMQUCBEESA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.9
• 重原子数：
  40
• 可旋转键数：
  21
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.51
• 拓扑面积：
  35
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  五羰基氯铼(I) 、 trans-4-methyl-4'-(2-(4-octadecyloxyphenyl)vinyl)-2,2'-bipyridine 以 苯 为溶剂， 以84%的产率得到tricarbonylchloro(trans-4-methyl-4'-(2-(4-octadecyloxyphenyl)vinyl)-2,2'-bipyridine)rhenium(I)
  参考文献：
  名称：

  Synthesis, Characterization, and Photoisomerization Studies of Azo- and Stilbene-Containing Surfactant Rhenium(I) Complexes

  摘要：

  A series of rhenium(I) surfactant complexes, fac-[Re(CO)(3)(N-N)(L)]PF6 (N-N = diimine, L = pyridyl ligand), with various azo- and stilbene-containing ligands have been synthesized and their photophysical properties studied. The X-ray crystal structure of the complex fac-[Re(CO)(3)(bpy)(L)]PF6 (bpy = 2,2'-bipyridine, L = 4-(4'-octadecyloxyphenylstyryl)pyridine) has been determined. The photoinduced isomerization processes of these complexes and their free ligands have been studied by electronic absorption and H-1 NMR spectroscopy, and their quantum yields determined.

  DOI：

  10.1021/om010192m