[Zn2(atp)2(bipy)2(H2O)4] | 959708-65-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Zn2(atp)2(bipy)2(H2O)4]
• 英文别名: [Zn2(2-aminoterephthalate)2(2,2'-bipyridine)2(H2O)4]
• CAS: 959708-65-7
• 化学式: C₃₆H₃₄N₆O₁₂Zn₂
• 分子量: 873.479
• InChiKey: FJGFKLPFGANRKD-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2,2'-联吡啶 、 2-氨基对苯二甲酸 、 zinc(II) nitrate hexahydrate 在 NaOH 作用下， 以 甲醇 、 水 为溶剂， 以60%的产率得到[Zn2(atp)2(bipy)2(H2O)4]
  参考文献：
  名称：

  Preparation and characterization of two three-dimensional metal–organic photoluminescent supramolecular networks

  摘要：

  Two novel photoluminescent coordination compounds of the formula [Cd(atpt)phen(H2O)] center dot H2O (1) and [Zn-2(atpt)(2)(biPY)(2)(H2O)(2)] (2) (H(2)atpt = 2-aminoterephthalic acid, bipy = 2,2'-bipyridine and phen = 1, 1 0-phenanthroline) were synthesized through the self-assembly of H2atpt and N-containing ligands (bipy for I and phen for 2) with metal(II) ions in the presence of NaOH, and were characterized by FT-IR spectroscopy, thermogravimetric analysis (TG), X-ray analysis and photoluminescence spectra in the solid state. Compound 1 is the first structurally characterized Cd(II) complex with the atpt ligand. The coordination mode of the atpt ligand in 2 is novel and is first reported in this presentation. X-ray crystallographic studies reveal that compound I shows a I D architecture. Compound 1 further assembles into a 3D supramolecular network via interchain hydrogen bonds and pi-pi stacking interactions. Compound 2 exhibits a binuclear structure with intramolecular pi-pi stacking interactions, which is further extended into a 3D supramolecular framework via intermolecular hydrogen bonds and C-H center dot center dot center dot pi interactions. Compounds 1 and 2 exhibit green photoluminescence in the solid state at room temperature. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.07.031