copper tetra(2,2'-dimethyl-4,5-benzodiazepino)porphyrazine | 519140-60-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: copper tetra(2,2'-dimethyl-4,5-benzodiazepino)porphyrazine
• 英文别名: copper;8,10,22,24,36,38,50,52-octamethyl-2,7,11,16,21,25,30,35,39,44,49,53,57,59-tetradecaza-58,60-diazanidatridecacyclo[43.11.1.13,15.117,29.131,43.04,14.06,12.018,28.020,26.032,42.034,40.046,56.048,54]hexaconta-1,3,5,7,10,12,14,16,18,20(26),21,24,27,29(59),30,32,34(40),35,38,41,43,45(57),46,48(54),49,52,55-heptacosaene
• CAS: 519140-60-4
• 化学式: C₅₂H₄₀CuN₁₆
• 分子量: 952.543
• InChiKey: OFNSLRHWQWAUHT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,2'-dimethyl-5,6-dicyanobenzodiazepine 、 copper diacetate 以 melt 为溶剂， 以27%的产率得到copper tetra(2,2'-dimethyl-4,5-benzodiazepino)porphyrazine
  参考文献：
  名称：

  摘要：

  4,5-Diaminophthalonitrile was reacted with carboxylic acids and acetylacetone to synthesize 2-alkyl-5,6-dicyanobenzimidazoles and 2,2'-dimethyl-5,6-dicyanobenzodiazepine, respectively. The products were converted into copper(II) porphyrazines. An effect of the heterocyclic residue on the, physicochemical and spectral properties of the porphyrazines was revealed.

  DOI：

  10.1023/a:1023343918982