N,N-Diisopropyl-2-phenylaniline | 132514-80-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N-Diisopropyl-2-phenylaniline
• 英文别名: 2-phenyl-N,N-di(propan-2-yl)aniline
• CAS: 132514-80-8
• 化学式: C₁₈H₂₃N
• 分子量: 253.387
• InChiKey: BMXPASRCCYCLMU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  19
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  biphenyl-2-yl trifluoromethanesulfonate 、 二异丙胺 在 正丁基锂 作用下， 生成 N,N-Diisopropyl-2-phenylaniline 、 N,N-Diisopropyl-3-phenylaniline
  参考文献：
  名称：

  Benzyne generation from aryl triflates

  摘要：

  The use of aryl triflates to form arynes as reactive intermediates is described. This allows the first general use of phenols as aryne precursors. Phenyl triflate reacts with LDA at - 78-degrees-C to form benzyne, which then reacts with diisopropylamine generating N,N-diisopropylaniline. Yields of diisopropylarylamines from aryne intermediates are superior to those previously reported. Regioisomeric ratios are similar to those obtained with use of other benzyne precursors.

  DOI：

  10.1021/jo00006a016

文献信息

• WICKHAM, PETER P.;HAZEN, KEVIN H.;GUO, HONG;JONES, GARTH;REUTER, KELLY HA+, J. ORG. CHEM., 56,(1991) N, C. 2045-2050
  作者：WICKHAM, PETER P.、HAZEN, KEVIN H.、GUO, HONG、JONES, GARTH、REUTER, KELLY HA+

  DOI：——

  日期：——
• ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES
  申请人：UNIVERSAL DISPLAY CORPORATION

  公开号：US20220127291A1

  公开（公告）日：2022-04-28

  A compound having a structure of Formula I In Formula I, M is Pd or Pt; each of X 1 to X 12 is independently C or N; ring A is a 5-membered or 6-membered ring; K 1 and K 2 are selected from a direct bond, O, S, and NR; L 1 is an organic linker; Y 1 is selected from O, S, BR, PR, Se and NR Y ; each R, R′, R″, R L , R Y , R A , R B , R C , and R D is hydrogen or a substituent; and any two substituents can be joined or fused to form a ring. Further provided are OLEDs and related consumer products that utilize these compounds.