1-[6-(2,2'-bipyridyl)]-1-(2-pyridyl)-ethanol | 852244-36-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 1-[6-(2,2'-bipyridyl)]-1-(2-pyridyl)-ethanol
• CAS: 852244-36-1
• 化学式: C₁₇H₁₅N₃O
• 分子量: 277.326
• InChiKey: NSFJRLCFNNSBCG-QGZVFWFLSA-N

反应信息

• 作为反应物：
  描述：

  1-[6-(2,2'-bipyridyl)]-1-(2-pyridyl)-ethanol 、 trans-[RuCl2(S-dmso)(4'-(4-methylphenyl)-2,2':6',2''-terpyridine)] 以 乙醇 、 水 为溶剂， 生成 [Ru(4'-tolyl-2,2':6',2''-terpyridine)(1-[6-(2,2'-bipyridyl)]-1-(2-pyridyl)-ethanol)](2+)
  参考文献：
  名称：

  Rapid electrochemically induced linkage isomerism in a ruthenium(ii) polypyridyl complex

  摘要：

  Rapid and complete switching between the N6 and the N5O donor set induced by changing the metal oxidation state has been observed for a new structural motif based on a ruthenium(II) polypyridyl complex.

  DOI：

  10.1039/b500946d

文献信息

• A New Strategy for the Improvement of Photophysical Properties in Ruthenium(II) Polypyridyl Complexes. Synthesis and Photophysical and Electrochemical Characterization of Six Mononuclear Ruthenium(II) Bisterpyridine-Type Complexes
  作者：Maria Abrahamsson、Henriette Wolpher、Olof Johansson、Jan Larsson、Mikael Kritikos、Lars Eriksson、Per-Ola Norrby、Jonas Bergquist、Licheng Sun、Björn Åkermark、Leif Hammarström

  DOI：10.1021/ic048247a

  日期：2005.5.1

  characterization of six ruthenium(II) bistridentate polypyridyl complexes is described. These were designed on the basis of a new approach to increase the excited-state lifetime of ruthenium(II) bisterpyridine-type complexes. By the use of a bipyridylpyridyl methane ligand in place of terpyridine, the coordination environment of the metal ion becomes nearly octahedral and the rate of deactivation via ligand-field

  描述了六种钌（II）双链状多吡啶基配合物的合成和表征。这些是在增加钌（II）双吡啶类配合物的激发态寿命的新方法的基础上设计的。通过使用联吡啶基吡啶基甲烷配体代替叔吡啶，金属离子的配位环境几乎变为八面体，并且通过配体场（即，以金属为中心）状态的失活速率降低，如温度相关的发射寿命所示。学习。仍然，在复合物中保持了制备准线性的供体-钌-受体三单元组的可能性。最有前途的复合物在室温下在醇溶液中的激发态寿命为tau = 15 ns，应该与[Ru（tpy）2] 2+的tau = 0.25 ns的寿命进行比较。新复合物的X射线结构确实比[Ru（tpy）2] 2+具有更八面体的几何形状。最重要的是，保留了高激发态能量，因此保留了被激发配合物的潜在高反应性，而先前发表的基于双链配合物的策略则不是这种情况。
• Surface modification of carbon and metal electrodes with bistable molecular redox switches by click and amide coupling
  作者：R. T. Jane、E. Gaudemer、R. Lomoth

  DOI：10.1039/c5tc01655j

  日期：——

  Ruthenium complexes [Ru(R-Ph-tpy)(bpyMeOHpy)] (Ph-tpy = 4′-(4-R-phenyl)-2,2′:6′,2′′-terpyridine, R = NH2, COOH, CCH, bpyMeOHpy = 1-[6-(2,2′-bipyridyl)]-1-(2-pyridyl)-ethanol) were covalently attached to carbon and metal electrodes by amide and click coupling reactions. Coupling agents were covalently grafted onto the electrodes by electrochemical reduction of p-functionalized diazonium tethers X-Ph-N2+

  钌配合物[Ru（R-Ph-tpy）（bpyMeOHpy）]（Ph-tpy = 4'-（4-R-苯基）-2,2'：6'，2''-叔吡啶，R = NH 2，通过酰胺和点击偶联反应将COOH，C CH，bpyMeOHpy = 1- [6-（2,2'-联吡啶基）]-1-（2-吡啶基-乙醇）共价连接到碳和金属电极上。通过电化学还原对-官能化的重氮系链X-Ph-N 2 +（X = COOH，NO 2，N 3），然后电化学还原硝基系链，将偶联剂共价接枝到电极上。用Ru络合物修饰电极表面会导致基于氧化还原诱导的N 6 / N 5的磁滞电流-电压响应bpyMeOHpy螯合物中的吡啶基/烷氧基单元的O键异构体。固定化的配合物可以用≤10000 V s -1的扫描速率进行电化学彻底处理，并可以通过动力学和热力学参数进行均匀切换，类似于参比配合物在均相溶液中的性质。