C,C',C''-C'''-(6-phenyl-[1,3,5]triazine-2,4-diylbisazanediyl)-tetrakis-methanol | 4407-82-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: C,C',C''-C'''-(6-phenyl-[1,3,5]triazine-2,4-diylbisazanediyl)-tetrakis-methanol
• 英文别名: [[4-[Bis(hydroxymethyl)amino]-6-phenyl-1,3,5-triazin-2-yl]-(hydroxymethyl)amino]methanol
• CAS: 4407-82-3
• 化学式: C₁₃H₁₇N₅O₄
• 分子量: 307.309
• InChiKey: XHECAORXOROLKA-UHFFFAOYSA-N

物化性质

• 熔点：
  132-142 °C
• 沸点：
  618.1±65.0 °C(Predicted)
• 密度：
  1.533±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.6
• 重原子数：
  22
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  126
• 氢给体数：
  4
• 氢受体数：
  9

反应信息

• 作为反应物：
  描述：

  C,C',C''-C'''-(6-phenyl-[1,3,5]triazine-2,4-diylbisazanediyl)-tetrakis-methanol 、 二丁氧基(二甲基)硅烷 以46%的产率得到
  参考文献：
  名称：

  XASIEVA, D. S.;XANANASHVILI, L. M., SOOBSHCH. AN GSSR, 1982, 107, N 3, 521-524

  摘要：

  DOI：
• 作为产物：
  描述：

  2,4-二氨基-6-苯基-1,3,5-三嗪 、 聚合甲醛 以80%的产率得到
  参考文献：
  名称：

  XASIEVA, D. S.;XANANASHVILI, L. M., SOOBSHCH. AN GSSR, 1982, 107, N 3, 521-524

  摘要：

  DOI：

文献信息

• Bottom antireflective coatings
  申请人：Yao Huirong

  公开号：US20050112494A1

  公开（公告）日：2005-05-26

  The present invention relates to bottom antireflective coating compositions and polymers useful in making such compositions.

  本发明涉及用于制备底部抗反射涂层组合物和聚合物的相关技术。
• Aminoplastharz, die Herstellung desselben und seine Verwendung
  申请人：CIBA-GEIGY AG

  公开号：EP0011049A1

  公开（公告）日：1980-05-14

  Das verlängerte Methyl- und Methylolgruppen enthaltende Guanaminharz wird durch Reaktion eines Guanamins der Formel I in der R eine Alkylgruppe, eine Phenylgruppe oder eine Gruppe beispielsweise der Formel bedeutet mit einer Verbindung wie Harnstoff, Melamin, Benzoguanamin oder dergleichen erhalten. Im Durchschnitt sind mindestens 70% der Gesamtzahl an den Gruppen R1 des Methyl-methylolgruppen enthaltenden Guanamins der Formel I Methylgruppen. Das Harz gemäss der Erfindung ist als Beschichtungsmaterial in Form von Lösungen oder Pulver hervorragend geeignet.

  含有拉长甲基和甲醇基团的胍胺树脂是由式 I 的胍胺反应得到的 其中 R 代表烷基、苯基或例如如下式的基团 表示 与尿素、三聚氰胺、苯并胍胺等化合物反应。平均而言，式 I 的含甲基-甲醇基团的鸟胺的基团 R1 总数中至少有 70% 是甲基基团。 本发明的树脂非常适合作为溶液或粉末状的涂层材料。
• Coating composition
  申请人：TORAY INDUSTRIES, INC.

  公开号：EP0065388A1

  公开（公告）日：1982-11-24

  Provided are coating-forming coating compositions comprising the following components A and B, preferably further including the following component C and/or D, and having superior surface hardness, abrasion resistance, flexibility, dyeability and durability, as well as coatings formed by curing such coating compositions: A. A vinyl polymer having a group represented by the general formula R1m(R2O)3-mSi- wherein R1 is methyl or ethyl, R2 is an alkyl, alkoxyalkyl or acyl group having not more than 4 carbon atoms, with silicon being attached to the polymer by Si-C bond, and m is 0, or 2. B. Fine particles of silica having an : verage diameter of particles in the range of about 1 to about 200 nm. C. A curing catalyst. D. At least one compound selected from the group consisting of acrylic resins, polyester resins, alkyd resins, epoxy resins, cellulose resins, amino resins and silicon compounds represented by the general formula R5aR6bSi(OR7)4-(a+b) wherein R5 and R6 are each an alkyl, alkenyl, aryl, halogenated alkyl or alkenyl group having 1 to 10 carbon atoms or an organic group having an epoxy, (meth)acryloxy or cyano group, bonded to silicon by Si-C bond, R7 is an alkyl, alkoxyalkyl or acyl group having 1 to 8 carbon atoms, a and b are each 0,1 or 2 provided a + b equals 0, or 2.

  本发明提供了由以下成分 A 和 B 组成的涂层形成涂料组合物，最好还包括以下成分 C 和/或 D，并具有优异的表面硬度、耐磨性、柔韧性、染色性和耐久性，以及通过固化此类涂料组合物形成的涂层： A.具有通式 R1m(R2O)3-mSi- 所代表基团的乙烯基聚合物 其中 R1 是甲基或乙基，R2 是烷基、烷氧基烷基或酰基，具有不超过 4 个碳原子，硅通过 Si-C 键连接到聚合物上，m 是 0 或 2。 B.二氧化硅细颗粒，其颗粒直径在约 1 至约 200 纳米之间。 C.固化催化剂。 D.至少一种选自丙烯酸树脂、聚酯树脂、醇酸树脂、环氧树脂、纤维素树脂、氨基树脂和由通式 R5aR6bSi(OR7)4-(a+b)表示的硅化合物所组成的组的化合物 其中 R5 和 R6 各为烷基、烯基、芳基、卤代烷基或烷基，具有约 10 个烷基、烯基、芳基或卤代烷基、R7 是具有 1 至 8 个碳原子的烷基、烷氧基烷基或酰基，a 和 b 分别为 0、1 或 2，条件是 a + b 等于 0 或 2。
• Low temperature-curing polyester urethane systems
  申请人：DeSOTO, INC.

  公开号：EP0172993A1

  公开（公告）日：1986-03-05

  An hydroxy-functional polyurethane reaction product is disclosed which enables the provision of thermosetting solution coating compositions which cure at low temperature to form flexible coatings. These polyurethanes are provided by the reaction of an organic diisocyanate with a stoichiometric excess of an essentially linear hydroxy-functional polyester which is the polyesterification reaction product of C4-C10 aliphatic dicarboxylic acid or anhydride thereof with a stoichiometric excess of C3-C8 aliphatic diol providing an alcohol/acid molar ratio of 3/2 to 6/5. The reaction is substantially complete as indicated by an acid number less than 10, and the diisocyanate is used in an amount providing an NCO/OH ratio of from 2/3 to 12/13. The thermosetting solution coating composition is provided by an organic solvent having dissolved therein from 5-50% of total resin solids of a curing agent reactive with hydroxy groups together with the polyurethane which has been described. The preferred curing agent is a partially methylolated melamine which contains from about 5 mol percent to about 40 mol percent of the methylol group.

  本发明公开了一种羟基官能团聚氨酯反应产物，可提供在低温下固化形成柔性涂层的热固性溶液涂料组合物。这种聚氨酯是由有机二异氰酸酯与一定量过量的基本线性羟基官能团聚酯反应生成的，该聚酯是 C4-C10 脂肪族二羧酸或其酸酐与一定量过量的 C3-C8 脂肪族二元醇聚酯化反应产物，醇/酸摩尔比为 3/2 至 6/5。反应基本完成，酸数小于 10，二异氰酸酯的用量为 NCO/OH 比 2/3 至 12/13。热固性溶液涂料组合物由一种有机溶剂提供，该有机溶剂中溶解有占树脂总固体份 5-50% 的与羟基反应的固化剂和所述的聚氨酯。首选的固化剂是部分甲醇化的三聚氰胺，其甲醇基含量约为 5 摩尔%至 40 摩尔%。
• Thermoplastic resin composition
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0343876A1

  公开（公告）日：1989-11-29

  The present invention provides a thermoplastic resin composition which is improved in compatibility between polyphenylene ether and polyamide and is excellent in processability and impact strength. This composition comprises: (A) 100 parts by weight of a composition comprising 95-5% by weight of a polyphenylene ether obtained by oxidation polymerization of one or more of phenol compounds represented by the following formula: (wherein R₁, R₂, R₃, R₄ and R₅ which may be identical or different, each represents a hydrogen atom, a halogen atom, a hydrocarbon radical or a substituted hydrocarbon radical and at least one of them is a hydrogen atom) and 5-95% by weight of a polyamide, (B) 0-30 parts by weight of an impact strength modifier, and (C) 0.01-10 parts by weight of an amino resin obtained by modifying with an alcohol an addition reaction product of formaldehyde and at least one compound selected from the group consisting of melamine, guanamine and urea.

  本发明提供了一种热塑性树脂组合物，该组合物改善了聚苯醚和聚酰胺之间的相容性，并具有优异的加工性和抗冲击强度。这种组合物包括 (A) 100 重量份的组合物，该组合物包含 95-5%（重量百分比）的聚苯醚，该聚苯醚 是由下式所代表的一种或多种苯酚化合物氧化聚合而成： (其中R₁、R₂、R₃、R₄和R₅可以相同或不同，各自代表氢原子、卤素原子、烃基或取代的烃基，且其中至少一个是氢原子）和5-95%（重量）的聚酰胺、 (B) 0-30 份（按重量计）抗冲击强度改性剂，及 (C) 0.01-10 份（按重量计）氨基树脂，该氨基树脂是通过将甲醛与至少一种选 自三聚氰胺、鸟嘌呤胺和尿素的化合物的加成反应产物与醇进行改性而得。