Perfluor-o-terphenyl | 21283-14-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Perfluor-o-terphenyl
• 英文别名: Perfluoro-o-terphenyl；Perfluoro-terphenyl；1,2,3,4,5-pentafluoro-6-[2,3,4,5-tetrafluoro-6-(2,3,4,5,6-pentafluorophenyl)phenyl]benzene
• CAS: 21283-14-7
• 化学式: C₁₈F₁₄
• 分子量: 482.176
• InChiKey: VQEZJTIPLFPILL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.6
• 重原子数：
  32
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  14

文献信息

• FLUORINATED AROMATIC COMPOUND, METHOD FOR ITS PRODUCTION, CURABLE MATERIAL, ITS CURED PRODUCT, AND OPTICAL MEMBER
  申请人：ASAHI GLASS COMPANY, LIMITED

  公开号：US20160137572A1

  公开（公告）日：2016-05-19

  To provide a novel fluorinated aromatic compound having at least two carbon-carbon unsaturated bonds, a method for its production, a curable material comprising the fluorinated aromatic compound, a cured product thereof, and an optical member. The fluorinated aromatic compound is represented by formula (A), wherein n is an integer of 0 to 6, a is an integer of 0 to 5, b is an integer of 0 to 4, c is an integer of 0 to 4, a+c+n is 2 to 6, a+b is 2 to 9, Z is a single bond, —O—, —S—, —CO—, —C(CH 3 ) 2 —, —C(CF 3 ) 2 —, —SO—, or —SO 2 —, Rf 1 is a C 1-8 fluoroalkyl group, Y 1 and Y 2 are each independently a group represented by formula (1) (s is 0 or 1, and R 1 , R 2 , R 3 , and R 4 are each independently a hydrogen atom or a fluorine atom), and F in the aromatic ring indicates that hydrogen atoms in the aromatic ring are all substituted by fluorine atoms.

  提供一种至少具有两个碳-碳不饱和键的新型氟芳香化合物，一种其生产方法，包括所述氟芳香化合物的可固化材料，其固化产物以及光学部件。所述氟芳香化合物由式（A）表示，其中n为0至6的整数，a为0至5的整数，b为0至4的整数，c为0至4的整数，a+c+n为2至6，a+b为2至9，Z为单键，—O—，—S—，—CO—，—C(CH3)2—，—C(CF3)2—，—SO—，或—SO2—，Rf1为C1-8氟烷基，Y1和Y2分别独立地表示由式（1）表示的基团（s为0或1，R1、R2、R3和R4分别独立地表示氢原子或氟原子），芳香环中的F表示芳香环中的氢原子均被氟原子取代。
• CROSSLINKABLE FLUOROAROMATIC PREPOLYMER AND USE THEREOF
  申请人：ASAHI GLASS COMPANY LTD.

  公开号：EP1669389A1

  公开（公告）日：2006-06-14

  To provide a crosslinkable fluorinated aromatic prepolymer which is capable of forming a cured product having a low relative permittivity, high heat resistance, low birefringence and high flexibility, and its uses. A crosslinkable fluorinated aromatic prepolymer which is obtained by subjecting a compound (Y-1) having a crosslinkable functional group (A) and a phenolic hydroxyl group and/or a compound (Y-2) having a crosslinkable functional group (A) and a fluorinated aromatic ring, to a condensation reaction in the presence of a HF-removing agent, with a fluorinated aromatic compound (B) represented by the formula (1): (wherein n is an integer of from 0 to 2, each of a and b which are independent of each other, is an integer of 0 to 3, and each of Rf1 and Rf2 represents a fluorinated alkyl group having at most 8 carbon atoms and a compound (C) having at least 3 phenolic hydroxyl groups, and which has crosslinkable functional groups (A) and ether bonds and has a number average molecular weight of from 1×103 to 5×105.

  提供一种可交联含氟芳香族预聚物，它能够形成具有低相对介电常数、高耐热性、低双折射和高柔韧性的固化产品及其用途。 一种可交联的氟化芳香族预聚物，它是将具有可交联官能团（A）和酚羟基的化合物（Y-1）和/或具有可交联官能团（A）和氟化芳香环的化合物（Y-2）与由式（1）表示的氟化芳香族化合物（B）在氢氟酸去除剂存在下进行缩合反应而得到的： (其中 n 为 0 至 2 的整数，a 和 b 互不相关，均为 0 至 3 的整数，Rf1 和 Rf2 分别代表具有至多 8 个碳原子的氟化烷基和具有至少 3 个酚羟基的化合物 (C)，该化合物具有可交联官能团 (A) 和醚键，其平均分子量为 1×103 至 5×105。
• CROSSLINKABLE FLUORINE-CONTAINING AROMATIC PREPOLYMER AND USE THEREOF
  申请人：Asahi Glass Company, Limited

  公开号：EP1897897A1

  公开（公告）日：2008-03-12

  To provide a crosslinkable fluorinated aromatic prepolymer which is capable of forming a cured product having high transparency, a low relative permittivity, high heat resistance, low birefringence and high flexibility, and its uses. A crosslinkable fluorinated aromatic prepolymer which is obtained by subjecting a compound (Y-1) having a polymerizable double bond (A) and/or a phenolic hydroxyl group and a compound (Y-2) having a polymerizable double bond (A) and a fluorinated aromatic ring, to a condensation reaction in the presence of a HF-removing agent, with a fluorinated aromatic compound (B) represented by the following formula (1): (wherein n is an integer of from 0 to 3, each of a and b which are independent of each other, is an integer of from 0 to 3, and each of Rf1 and Rf2 is a fluorinated alkyl group having at most 8 carbon atoms), and a compound (C) having at least 3 phenolic hydroxyl groups, the respective phenolic hydroxyl groups not being present in the same aromatic ring, and which has polymerizable double bonds (A) and ether bonds and has a number average molecular weight of from 1×103 to 5×105.

  提供一种可交联的含氟芳香族预聚物，它能够形成具有高透明度、低相对介电常数、高耐热性、低双折射和高柔韧性的固化产品及其用途。 一种可交联的含氟芳香族预聚物，它是将具有可聚合双键（A）和/或酚羟基的化合物 （Y-1）和具有可聚合双键（A）和含氟芳香环的化合物（Y-2）与下式（1）表示的含氟芳香族化合物 （B）在氢氟酸去除剂存在下进行缩合反应而得到的： (其中 n 为 0 至 3 的整数，a 和 b 互不相关，均为 0 至 3 的整数，Rf1 和 Rf2 均为最多具有 8 个碳原子的氟化烷基)，以及至少具有 3 个酚羟基的化合物(C)，各酚羟基不存在于同一芳香环中，该化合物具有可聚合双键(A)和醚键，平均分子量为 1×103 至 5×105。
• CROSSLINKABLE PREPOLYMER, PROCESS FOR PRODUCTION THEREOF, AND USE THEREOF
  申请人：Asahi Glass Company, Limited

  公开号：EP2025698A1

  公开（公告）日：2009-02-18

  To provide a prepolymer which is excellent in heat resistance and which can form a cured product excellent in oil repellency and water repellency. A crosslinkable prepolymer having a polyaryl ether structure on its main chain, which has a crosslinkable functional group and a side chain represented by "Rf-CH2-O-" wherein Rf is a C3-50 fluorinated alkyl group (which may contain an oxygen atom forming an ether bond)).

  提供一种耐热性能优异的预聚物，它可以形成憎油性和憎水性优异的固化产品。 一种主链上具有聚芳醚结构的可交联预聚物，它具有可交联的官能团和以 "Rf-CH2-O-"表示的侧链，其中 Rf 是 C3-50 氟化烷基（可含有一个形成醚键的氧原子））。
• PREPOLYMER, CURABLE MATERIAL, COATING COMPOSITION, NON-LINEAR OPTICAL MATERIAL, OPTICAL WAVEGUIDE AND LIGHT CONTROL DEVICE
  申请人：Asahi Glass Company, Limited

  公开号：EP2889684A1

  公开（公告）日：2015-07-01

  Provided are: a prepolymer which is capable of forming a non-linear optical material that has excellent non-linear optical effect, heat resistance, withstand voltage and transparency; a curable material which contains the prepolymer; a coating composition which contains the curable material and a solvent; a non-linear optical material which is obtained by curing the curable material; an optical waveguide which uses the non-linear optical material; and a light control device which is provided with the optical waveguide. The present invention uses a prepolymer having a crosslinkable functional group, which is obtained by reacting one or more compounds (X) that are selected from the group consisting of compounds (X1), compounds (X2) and compounds (X3), a compound (Y) that is represented by formula (Y), a compound (Z) that has three or more phenolic hydroxyl groups, and an organic compound (B) that exerts a non-linear optical effect and has a reactive group.

  本发明提供了：一种能够形成非线性光学材料的预聚物，该材料具有优异的非线性光学效果、耐热性、耐电压性和透明度；一种包含该预聚物的可固化材料；一种包含该可固化材料和溶剂的涂层组合物；一种通过固化该可固化材料而获得的非线性光学材料；一种使用该非线性光学材料的光波导；以及一种配备该光波导的光控制装置。本发明使用了一种具有可交联官能团的预聚物，该预聚物是通过将一种或多种选自化合物（X1）、化合物（X2）和化合物（X3）组成的组的化合物（X）、由式（Y）表示的化合物（Y）、具有三个或多个酚羟基的化合物（Z）和具有非线性光学效应并具有活性基团的有机化合物（B）反应而得到的。