[(PPh3)AgNO2(2,9-dimethylphenanthroline)] | 1000595-09-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [(PPh3)AgNO2(2,9-dimethylphenanthroline)]
• 英文别名: [(PPh3)AgNO2(dmp)]
• CAS: 1000595-09-4
• 化学式: C₃₂H₂₇AgN₃O₂P
• 分子量: 624.427
• InChiKey: JXYWKZPRWFBLCP-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  新铜试剂 、 silver(I) nitrite*triphenylphosphine 以 苯 为溶剂， 以50%的产率得到[(PPh3)AgNO2(2,9-dimethylphenanthroline)]
  参考文献：
  名称：

  Adducts of silver(I) nitrite with triphenylphosphine and N,N′-bidentate aromatic bases, L, of the form AgNO2:PPh3:L (1:1:1)

  摘要：

  Adducts of the form AgNO2:PPh3: L (1:1:1) (L=2,2'-bipyridyl (bpy), 1,10-phenanthroline (phen), 2,9-dimethylphenanthroline (dmp)) have been synthesized and characterized by analytical, spectroscopic (IR, far-IR, H-1 and P-31 NMR) studies, together with a single crystal X-ray study for the L = dmp adduct, for comparison with the recently reported counterpart adducts of silver(l) nitrate. While the silver(l) coordination environment is still dominated by the quasi-planar N2AgP motif (Ag-P 2.378(1), Ag-N 2.364(3), 2.392(4) angstrom), the interaction of the nitrite is symmetrical (Ag-O 2.512(4), 2.543(5) angstrom) and invasive, the PAgN2 angle sum diminished to 324.7 degrees. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2006.11.010