4,8-dihydroxy-1-phenylanthra[1,2-c]furan-3,6,11(1H)-trione | 1021158-61-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 4,8-dihydroxy-1-phenylanthra[1,2-c]furan-3,6,11(1H)-trione
• CAS: 1021158-61-1
• 化学式: C₂₂H₁₂O₆
• 分子量: 372.334
• InChiKey: UAYAZQZGNNVCSQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.13
• 重原子数：
  28.0
• 可旋转键数：
  1.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  100.9
• 氢给体数：
  2.0
• 氢受体数：
  6.0

反应信息

• 作为产物：
  描述：

  4-methoxymethoxy-1-phenylnaphtho[1,2-c]furan-3,6,9(1H)-trione 、 反-1-甲氧基-3-(三甲基硅氧基)-1,3-丁二烯 生成 4,8-dihydroxy-1-phenylanthra[1,2-c]furan-3,6,11(1H)-trione 、 4,9-dihydroxy-1-phenylanthra[1,2-c]furan-3,6,11(1H)-trione
  参考文献：
  名称：

  Synthetic studies on basidifferquinones: the first synthesis of (±)-basidifferquinone C

  摘要：

  Basidifferquinones, isolated from Streptonzyces sp., are potent inducers for fruiting-body formation of a basidiomycete Polyporus arcularius. Construction of the basic framework of basidifferquinones and the first synthesis of (+/-)-basidifferquinone C were accomplished by starting from 3,5-dihydroxy-2-naphthoic acid. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2008.02.011

文献信息

• First Synthesis of (±)-Basidifferquinone C, an Inducer for Fruiting-Body Formation in<i>Polyporus arcularius</i>
  作者：Takashi HASHIMOTO、Takuya TASHIRO、Takeshi KITAHARA、Kenji MORI、Mitsuru SASAKI、Hirosato TAKIKAWA

  DOI：10.1271/bbb.90408

  日期：2009.10.23

  Basidifferquinones, isolated from Streptomyces sp., are potent inducers of fruiting-body formation in the basidiomycete, Polyporus arcularius. The first synthesis of (±)-basidifferquinone C was accomplished by starting from 3,5-dihydroxy-2-naphthoic acid.

  从链霉菌（Streptomyces sp.）中分离出的基底ifferquinones（基底ifferquinones）是基原真菌多孔菌（Polyporus arcularius）子实体形成的强效诱导剂。(±)-basidifferquinone C 的首次合成是从 3,5-二羟基-2-萘酸开始的。