3-{(E)-[4-(adamantan-1-ylcarbonyloxy)-3-ethoxyphenyl]methylideneamino}benzoic acid | 1240895-10-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚酯
• 英文名称: 3-{(E)-[4-(adamantan-1-ylcarbonyloxy)-3-ethoxyphenyl]methylideneamino}benzoic acid
• CAS: 1240895-10-6
• 化学式: C₂₇H₂₉NO₅
• 分子量: 447.531
• InChiKey: GPPSRVFDASAMFC-LQKURTRISA-N

反应信息

• 作为产物：
  描述：

  3-ethoxy-4-(1-adamantylcarbonyloxyl)benzaldehyde 、 间氨基苯甲酸 以 甲醇 为溶剂， 以90%的产率得到3-{(E)-[4-(adamantan-1-ylcarbonyloxy)-3-ethoxyphenyl]methylideneamino}benzoic acid
  参考文献：
  名称：

  Synthesis and properties of (E)-4-[alkyl(aryl)iminomethyl]-2-methoxy(ethoxy)phenyl adamantane-1-carboxylates

  摘要：

  Condensation of 4-formyl-2-methoxy(ethoxy)phenyl adamantane-1-carboxylates with aliphatic, cycloaliphatic, and aromatic amines gave the corresponding adamantane-containing Schiff bases as E isomers with respect to the CH=N azomethine bond. The reaction of 2-methoxy-4-(naphthalen-2-yliminomethyl)phenyl adamantane-1-carboxylate with cyclohexane-1,3-dione and dimedone led to the formation of 2-methoxy-4-(11-oxo-7,8,9,10,11,12-hexahydrobenzo[a]acridin-12-yl)phenyl adamantane-1-carboxylates. Quantum-chemical calculations of the energies of formation of E and Z isomers of some of the synthesized Schiff bases were performed.

  DOI：

  10.1134/s107042801004010x