bis(3,6-di-tert-butyl-catecholate)bis(diethyl ether)germanium(IV) | 1148042-04-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(3,6-di-tert-butyl-catecholate)bis(diethyl ether)germanium(IV)
• CAS: 1148042-04-9
• 化学式: C₃₆H₆₀GeO₆
• 分子量: 661.459
• InChiKey: XDBCMCKESJMCDJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  germanium(II) chloride dioxane 、 乙醚 、 3,6-二叔丁基环己-3,5-二烯-1,2-二酮 以 乙醚 为溶剂， 以82.3%的产率得到bis(3,6-di-tert-butyl-catecholate)bis(diethyl ether)germanium(IV)
  参考文献：
  名称：

  Novel germanium(IV) catecholate complexes

  摘要：

  The interaction of germanium(II) chloride dioxanate with 3,6-di-tert-butyl-o-benzoquinone or with its mono- and dianion derivatives is attended by the redox transformations. The novel germanium bis-catecholate complexes were synthesized that contained coordinated ether molecules (THF (I), Et2O (II)) irrespective of the initial redox form of o-quinone. The germanium complex was also synthesized by the exchange reaction between GeCl4 and sodium catecholate. Complexes (I), (II) were characterized by NMR and IR spectroscopies, elemental and X-ray diffraction analyses.

  DOI：

  10.1134/s1070328408040027