[Zn(phthalocyanine(4-tert-butylphenyl)4)]2 | 1094613-45-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Zn(phthalocyanine(4-tert-butylphenyl)4)]2
• CAS: 1094613-45-2
• 化学式: C₁₄₄H₁₂₈N₁₆O₈Zn₂
• 分子量: 2341.48
• InChiKey: SIRLPHNAODDFEW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Zn(phthalocyanine(4-tert-butylphenyl)4)]2 以 甲醇 、 氯仿 为溶剂， 生成 zinc 1,8(11),15(18),22(25)-tetra(4-tert-butylphenoxy)phthalocyanine
  参考文献：
  名称：

  Tuning J-type dimers of non-peripherally substituted zinc tetra-4-tert-butylphenophthalocyanine

  摘要：

  It was found, by UV-vis and TOF-MS, that the head-to-tail dimers of non-peripherally substituted zinc tetra-4-tert-butylphenophthalocyanine are inclined to form in non-coordinated solvent, e.g. chloroform and especially in dilute solution under 1.25 x 10(-6) mol/mL. The aforementioned dimers in solution can be tuned by altering concentration or adding coordinated solvent, e.g. methanol, which might be further improved to a practical strategy for preparation of J-aggregates in the future. (c) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2008.04.017
• 作为产物：
  描述：

  zinc 1,8(11),15(18),22(25)-tetra(4-tert-butylphenoxy)phthalocyanine 以 氯仿 为溶剂， 生成 [Zn(phthalocyanine(4-tert-butylphenyl)4)]2
  参考文献：
  名称：

  Tuning J-type dimers of non-peripherally substituted zinc tetra-4-tert-butylphenophthalocyanine

  摘要：

  It was found, by UV-vis and TOF-MS, that the head-to-tail dimers of non-peripherally substituted zinc tetra-4-tert-butylphenophthalocyanine are inclined to form in non-coordinated solvent, e.g. chloroform and especially in dilute solution under 1.25 x 10(-6) mol/mL. The aforementioned dimers in solution can be tuned by altering concentration or adding coordinated solvent, e.g. methanol, which might be further improved to a practical strategy for preparation of J-aggregates in the future. (c) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2008.04.017