[Cu(pyridine)4(NO3)2] | 55667-88-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Cu(pyridine)4(NO3)2]
• 英文别名: copper;pyridine;dinitrate
• CAS: 55667-88-4
• 化学式: C₂₀H₂₀CuN₆O₆
• 分子量: 503.961
• InChiKey: GQNIWNJQPMYLOM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.85
• 重原子数：
  33
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  177
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  [Cu(pyridine)4(NO3)2]*(tetrahydrofuran)2 以 solid 为溶剂， 生成 [Cu(pyridine)4(NO3)2]
  参考文献：
  名称：

  Thermal dissociation processes for clathrates [CuPy₄(No₃)₂]·2g (G=tetrahydrofurane, chloroform)

  摘要：

  The thermal dissociation processes of clathrates [CuPy4(NO3)(2)].2G (G=tetrahydrofuran, chloroform) were studied. Thermodynamic parameters (DeltaH(av)(0), DeltaS(298)(0) and DeltaG(298)(0)) of the processes, producing solid host complex [CuPy4(NO3)(2)] and gaseous guest (G), were determined from the strain measurements. These data are compared with previous data for clathrates of the host complex with benzene and pyridine. Quasi-equilibrium thermogravimetry was used to investigate the step-by-step character of the dissociation processes. Kinetic studies were carried out for clathrate [CuPy4(NO3)(2)].2THF.

  DOI：

  10.1023/b:jtan.0000017354.10431.ee