[Zn(2-[N'-(1-acetyl-2-oxopropylidene)hydrazino]benzoic acid(-1H))2(2,2'-bipyridine)] | 1421765-20-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: [Zn(2-[N'-(1-acetyl-2-oxopropylidene)hydrazino]benzoic acid(-1H))2(2,2'-bipyridine)]
• CAS: 1421765-20-9
• 化学式: C₃₄H₃₀N₆O₈Zn
• 分子量: 716.038
• InChiKey: ABMMNQQPZVUHOQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-(2-(2,4-dioxopentan-3-ylidene)hydrazineyl)benzoic acid 、 Zn(II)(2,2'-bipyridyl)(NO3)2*H2O 以 乙醇 、 N,N-二甲基甲酰胺 为溶剂， 反应 18.5h， 以57%的产率得到[Zn(2-[N'-(1-acetyl-2-oxopropylidene)hydrazino]benzoic acid(-1H))2(2,2'-bipyridine)]
  参考文献：
  名称：

  Complexes of Zn(II) containing (o-)/(p-) carboxylato phenyl azo pentane 2,4-dione and 2,2′ bipyridine as ligands: Synthesis, characterization, colorimetric and fluorometric modulation in the presence of Ag+ ions

  摘要：

  Azo-enol based ligands 2-[N'-(1-acetyl-2-oxo-propylidene) hydrazino]-benzoic acid (L1H2) and 4-[N'-(1 acetyl-2 oxo-propylidene)-hydrazino]-benzoic acid (L2H2) and their complexes [Zn(L1H)(2)(bpy)] (1) and [Zn(L2H)(2)(bpy)] (2) (where bpy = 2, 2'-bipyridine) have been synthesized and characterized using elemental analyses, spectral (FT-IR, H-1 NMR, C-13 NMR, electronic absorption), emission and single-crystal X-ray diffraction studies. Complexes 1 and 2 display selective chromogenic and fluorogenic responses with Ag+ ions in the presence of several other metal ions. The binding is monitored separately using UV-Vis, fluorescence and H-1 NMR spectral titrations. Job's plot supports a 1:2 stoichiometry for 1 and 2 with Ag+ ions. The pH dependent "on-off" switching of fluorescence from complexes 1 and 2 have been studied. The fluorescence intensity quenches (turns-off) upon addition of OH- ions, while it enhances (turns-on) in the presence of H+ ions. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.11.012