(PPh4)[Ni(maleamido-nitrilo-dithiolate)2] | 853077-53-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (PPh4)[Ni(maleamido-nitrilo-dithiolate)2]
• CAS: 853077-53-9
• 化学式: C₈H₄N₄NiO₂S₄*C₂₄H₂₀P
• 分子量: 714.496
• InChiKey: OYRMTYGBKBGMGI-WEWFPKOMSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  44.0
• 可旋转键数：
  6.0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  133.76
• 氢给体数：
  2.0
• 氢受体数：
  8.0

反应信息

• 作为产物：
  描述：

  四苯基鏻 在 sodium methanethiolate 作用下， 以 甲醇 为溶剂， 生成 (PPh4)[Ni(maleamido-nitrilo-dithiolate)2]
  参考文献：
  名称：

  A Straightforward Synthesis of Diverse Nickel Dithiolene Complexes Appended with Hydrogen-Bond Donor/Acceptor Groups

  摘要：

  Nickel dithiolene complexes symmetrically appended with hydrogen-bond donor/acceptor functionalities such as imide, amide, or cyano/ amide groups have been synthesized by a straightforward method of wide applicability starting from one single precursor. Single-crystal X-ray structures reveal the occurrence of one type of ribbon common to all compounds that is based on a recurrent self-complementary intermolecular hydrogen-bonded ring motif linking the symmetrically substituted complexes.

  DOI：

  10.1021/ic050174n