3,3''-((1E,1'E)-(((1R,2R)-cyclohexane-1,2-diyl)bis(azaneylylidene))bis(methaneylylidene))bis(([1,1'-biphenyl]-2-ol)) | 929705-56-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,3''-((1E,1'E)-(((1R,2R)-cyclohexane-1,2-diyl)bis(azaneylylidene))bis(methaneylylidene))bis(([1,1'-biphenyl]-2-ol))
• CAS: 929705-56-6
• 化学式: C₃₂H₃₀N₂O₂
• 分子量: 474.602
• InChiKey: RPMKJQVWNNRBJJ-XHWZHIRMSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.28
• 重原子数：
  36.0
• 可旋转键数：
  6.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  65.18
• 氢给体数：
  2.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  3,3''-((1E,1'E)-(((1R,2R)-cyclohexane-1,2-diyl)bis(azaneylylidene))bis(methaneylylidene))bis(([1,1'-biphenyl]-2-ol)) 在 sodium tetrahydroborate 作用下， 生成 (1R,2R)-N,N'-bis(3-phenylsalicyl)cyclohexane-1,2-diamine
  参考文献：
  名称：

  PROCESS FOR PRODUCING OPTICALLY ACTIVE EPOXY COMPOUND, COMPLEX FOR USE IN THE PROCESS, AND PROCESS FOR PRODUCING THE SAME

  摘要：

  公开号：

  EP1849778B1

文献信息

• Method for Production of Optically Active Epoxy Compound, and Complex Used Therefor and Process for Producing the Same
  申请人：Katsuki Tsutomu

  公开号：US20080071099A1

  公开（公告）日：2008-03-20

  There is provided a method for industrially producing optically active epoxy compounds by asymmetrically epoxidizing prochiral unsaturated compounds with an oxidant using as a catalyst a single substance or a di-μ-oxo dimer derived therefrom represented by any of the following formulae (I), (I′), (II), (II′), (III), (III′), (IV), and (IV′): [wherein R 1 s are independently an alkyl group or an aryl group; R 2 s are independently an alkyl group or an aryl group; R 3 s are independently an alkyl group or an aryl group, provided that two R 3 s may be bonded with each other to form a ring; R 4 s are independently a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, a nitro group, or a cyano group; M is TiY 2 (Y is Cl, alkoxide, or a μ-oxo ligand)].
• METHOD FOR PRODUCTION OF OPTICALLY ACTIVE EPOXY COMPOUND, AND COMPLEX USED THEREFOR AND PROCESS FOR PRODUCING THE SAME
  申请人：KATSUKI Tsutomu

  公开号：US20120178954A1

  公开（公告）日：2012-07-12

  A complex, and a process for producing the same, represented by any of the following formulae (I), (I′), (II), (II′), (III), (III′), (IV), and (IV′): where: R 1 s are independently an alkyl group or an aryl group; R 2 s are independently a hydrogen atom, an alkyl group, or an aryl group; R 3 s are independently an alkyl group or an aryl group, provided that two R 3 s are optionally bonded with each other to form a ring; R 4 s are independently a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, a nitro group, or a cyano group; and M is TiY 2 , where Y is Cl or alkoxide or the complex forms a di-μ-oxo dimer where Y is a μ-oxo ligand.
• US8163941B2
  申请人：——

  公开号：US8163941B2

  公开（公告）日：2012-04-24
• US8410295B2
  申请人：——

  公开号：US8410295B2

  公开（公告）日：2013-04-02