[Cu(di[4-(pyridin-2-yl)pyrimidinyl]sulfide)][NO3]2 | 1352306-61-6

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: [Cu(di[4-(pyridin-2-yl)pyrimidinyl]sulfide)][NO3]2
• 英文别名: [Cu(2-pps)2][NO3]2
• CAS: 1352306-61-6
• 化学式: C₁₈H₁₂CuN₈O₆S
• 分子量: 531.955
• InChiKey: VELPPVRHPKIFNL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  di[4-(pyridin-2-yl)pyrimidinyl]disulfide 、 copper(II) nitrate 以 甲醇 、 甲苯 为溶剂， 以32%的产率得到[Cu2(di[4-(pyridin-2-yl)pyrimidinyl]trisulfide)2][NO3]2
  参考文献：
  名称：

  Variable transformations of di[4-(pyridin-2-yl)pyrimidinyl]disulfide induced by different metal salts

  摘要：

  Assembly of three different metal salts with 2-ppds (2-ppds = di[4-(pyridin-2-yl)pyrimidinyl]disulfide) under the same conditions produced three totally distinct coordination compounds. In the presence of Cu(NO3)(2), a dinuclear Cu(I) macrocyclic compound [Cu-2(2-ppts)(2)](NO3)(2) (1) together with a mononuclear Cu(II) compound [Cu(2-pps)](NO3)(2) (2) are formed, of which the initial 2-ppds ligand is in situ converted into its trisulfide 2-ppts (2-ppts = di[4-(pyridin-2-yl)pyrimidinyl]trisulfide) and monosulfide 2-pps (2-PPs = di[4-(pyridin-2-yl)pyrimidinyl]sulfide), respectively. Replacement of Cu(NO3)(2) by Zn(NO3)(2) affords a mononuclear Zn(II) coordination compound [Zn(2-pps)(NO3)(2)] (3). The use of HgCl2 results in a dinuclear Hg(II) compound [Hg4Cl8(2-ppds)(2)] (4) without any change on 2-ppds. All coordination compounds have been structurally ascertained by X-ray crystallography. Besides, ESI-MS examination of the mother solution for each compound has also been carried out to further understand the impacts of different metal salts. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.11.025