9,10-(9,9-bisfluorenyl)-1-decene | 204066-33-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: 9,10-(9,9-bisfluorenyl)-1-decene
• 英文别名: 9-[1-(9H-fluoren-9-yl)dec-9-en-2-yl]-9H-fluorene
• CAS: 204066-33-1
• 化学式: C₃₆H₃₆
• 分子量: 468.682
• InChiKey: FZSSXZUYFOYVIR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.1
• 重原子数：
  36
• 可旋转键数：
  10
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.28
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  氯化锆(IV) 、 9,10-(9,9-bisfluorenyl)-1-decene 在 正丁基锂 作用下， 以 乙醚 、 正己烷 为溶剂， 生成 9,10-η(5),η(5)-(9,9-bisfluorenylidene)-1-decene zirconium dichloride
  参考文献：
  名称：

  C2-bridged metallocene dichloride complexes of the types (C13H8–CH2CHR–C9H6−nR′n)ZrCl2 and (C13H8–CH2CHR–C13H8)MCl2 (n=0, 1; R=H, alkenyl; R′=alkenyl, benzyl; M=Zr, Hf) as self-immobilizing catalyst precursors for ethylene polymerization

  摘要：

  A total of 15 C-2-bridged fluorenylidene indenylidene and bis(fluorenylidene) metal dichloride complexes (metal = Zr, Hf) and the corresponding ligand precursors have been prepared and characterized. omega-Alkenyl substituents with various chain lengths in the C-2-bridge or in position 3 of the indenylidene moiety have an impact on the polymerization activity of the catalysts and the molecular weights of the produced polyethylenes. These omega-alkenyl substituents cause 'self-immobilization' due to their incorporation into the backbone of a growing polymer chain providing heterogeneous catalyst systems. (C) 1999 Published by Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00736-0
• 作为产物：
  描述：

  1,9-癸二烯 在 p-chloroperbenzoic acid 作用下， 以 二氯甲烷 为溶剂， 生成 9,10-(9,9-bisfluorenyl)-1-decene
  参考文献：
  名称：

  C2-bridged metallocene dichloride complexes of the types (C13H8–CH2CHR–C9H6−nR′n)ZrCl2 and (C13H8–CH2CHR–C13H8)MCl2 (n=0, 1; R=H, alkenyl; R′=alkenyl, benzyl; M=Zr, Hf) as self-immobilizing catalyst precursors for ethylene polymerization

  摘要：

  A total of 15 C-2-bridged fluorenylidene indenylidene and bis(fluorenylidene) metal dichloride complexes (metal = Zr, Hf) and the corresponding ligand precursors have been prepared and characterized. omega-Alkenyl substituents with various chain lengths in the C-2-bridge or in position 3 of the indenylidene moiety have an impact on the polymerization activity of the catalysts and the molecular weights of the produced polyethylenes. These omega-alkenyl substituents cause 'self-immobilization' due to their incorporation into the backbone of a growing polymer chain providing heterogeneous catalyst systems. (C) 1999 Published by Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00736-0