| 502627-24-9

• 分子结构分类: 有机化合物 - 苯类化合物 - N-苯基羟胺
• CAS: 502627-24-9
• 化学式: C₁₈H₂₀GeN₂Se
• 分子量: 415.92
• InChiKey: MJDOWQPMBSUEDH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  以 乙醚 、 甲苯 为溶剂， 生成
  参考文献：
  名称：

  Heteronuclear Multiple Bonding between Heavier Group 14 and 16 Elements. A New Class of Germylated Compounds, the Germanethiocarbamyl and Germaneselenocarbamyl Chlorides L²(Cl)GeY (Y = S, Se)

  摘要：

  The first monomeric germanethiocarbamyl halides containing a chelating beta-diiminate ligand, L-2(CI)Ge=Y (L-2 = PhNC(Me)CHC(Me)NPh; Y = S (2), Y = Se (3)), have been prepared by the reaction of the corresponding heteroleptic halogermylene L-2(Cl)Ge (1) with elemental sulfur or black selenium in refluxing toluene. Single-crystal X-ray structural analyses of 2 and 3 reveal that the germanium centers reside in highly distorted tetrahedral environments in these compounds; short Ge-Y distances (Ge-S = 2.07 Angstrom (2); Ge-Se = 2.21 Angstrom (3)) are indicative of an unsaturated character of these germanium-chalcogen bonds. Selective reactions between 2 or 3 and MeLi afforded the corresponding alkylated germanechalcogenones L-2(Me)Ge=Y (Y = S (4), Se (5)).

  DOI：

  10.1021/om0208974