({4-[4-(4-{4-[(diethoxyphosphino)methyl]phenyl}-2,3,5,6-tetrafluoro-phenyl)-2,3,5,6-tetrafluorophenyl]phenyl}methyl)diethoxy-phosphine | 287181-28-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: ({4-[4-(4-{4-[(diethoxyphosphino)methyl]phenyl}-2,3,5,6-tetrafluoro-phenyl)-2,3,5,6-tetrafluorophenyl]phenyl}methyl)diethoxy-phosphine
• 英文别名: [4-[4-[4-[4-(Diethoxyphosphanylmethyl)phenyl]-2,3,5,6-tetrafluorophenyl]-2,3,5,6-tetrafluorophenyl]phenyl]methyl-diethoxyphosphane
• CAS: 287181-28-6
• 化学式: C₃₄H₃₂F₈O₄P₂
• 分子量: 718.56
• InChiKey: KODJZHVQHRNMSW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.3
• 重原子数：
  48
• 可旋转键数：
  15
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  36.9
• 氢给体数：
  0
• 氢受体数：
  12

文献信息

• Blue light-emitting polymer prepared using a fluorinated tetraphenyl monomer and an EL device manufactured using the polymer
  申请人：——

  公开号：US20010021464A1

  公开（公告）日：2001-09-13

  Provided are a light-emitting polymer and its preparation method, the polymer being excellent in electron injection and transport ability as well as hole injection and transport ability in an EL device, the EL device manufactured from the polymer being also emittable in the blue emission region, in which the EL device from an inorganic material is not mostly emittable. The light-emitting polymer of the invention is an alternated copolymer having repeated units (arylenevinylene units) excellent in hole injection and transport ability and repeated units (fluorinated tetraphenyl units) excellent in electron injection and transport ability with alternated order, as shown in formula (II). Also provided are an EL device manufactured from the light-emitting polymer, a fluorinated tetraphenyl derivative of formula (I), which is used as a monomer to prepare the light-emitting polymer, and their preparation methods.

  本发明提供了一种发光聚合物及其制备方法，该聚合物具有优异的电子注入和传输能力，以及在电致发光器件中的空穴注入和传输能力，用该聚合物制造的电致发光器件还可在蓝色发射区域发光，而用无机材料制造的电致发光器件则大多不能发光。如式（II）所示，本发明的发光聚合物是一种交替共聚物，具有空穴注入和传输能力优异的重复单元（芳基乙烯单元）和电子注入和传输能力优异的重复单元（氟化四苯基单元）。此外，还提供了由该发光聚合物、用作制备该发光聚合物单体的式(I)的氟化四苯基衍生物及其制备方法制成的电致发光器件。
• US6495273B1
  申请人：——

  公开号：US6495273B1

  公开（公告）日：2002-12-17
• US6590125B2
  申请人：——

  公开号：US6590125B2

  公开（公告）日：2003-07-08