| 211937-39-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 211937-39-2
• 化学式: C₁₄H₂₃BO₂Si₂
• 分子量: 290.317
• InChiKey: YAAQXVMDROYHMY-UHFFFAOYSA-N

物化性质

• 沸点：
  283.2±23.0 °C(Predicted)
• 密度：
  0.91±0.1 g/cm3(Temp: 20 °C; Press: 760 Torr)(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.28
• 重原子数：
  19.0
• 可旋转键数：
  7.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  18.46
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  在 di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium 作用下， 以 neat (no solvent) 为溶剂， 以80%的产率得到
  参考文献：
  名称：

  Synthesis of difunctional borasiloxanes and their behavior in metathesis reactions

  摘要：

  New divinyl- and diallyl-borasiloxanes have been synthesized in good yield from corresponding boronic acids. They have been characterized by H-1-, C-13-, Si-29- and B-11-NMR, as well as by MS. Their behavior in metathesis reactions initiated by two different catalysts ([RhCl(COD)](2) for vinylsiloxanes and [Mo] Schrock's catalyst for allylsiloxanes) has been studied. This has led to new cycloborasiloxanes that have been characterized. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00498-7
• 作为产物：
  描述：

  二甲基乙烯基氯硅烷 、 苯硼酸 在 三乙胺 作用下， 以 乙醚 为溶剂， 以84%的产率得到
  参考文献：
  名称：

  Synthesis of difunctional borasiloxanes and their behavior in metathesis reactions

  摘要：

  New divinyl- and diallyl-borasiloxanes have been synthesized in good yield from corresponding boronic acids. They have been characterized by H-1-, C-13-, Si-29- and B-11-NMR, as well as by MS. Their behavior in metathesis reactions initiated by two different catalysts ([RhCl(COD)](2) for vinylsiloxanes and [Mo] Schrock's catalyst for allylsiloxanes) has been studied. This has led to new cycloborasiloxanes that have been characterized. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00498-7