2,4-dichloro-6-[(3-methylaminopropylimino)methyl]phenol | 1051457-04-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,4-dichloro-6-[(3-methylaminopropylimino)methyl]phenol
• 英文别名: 2,4-Dichloro-6-(((3-(methylamino)propyl)imino)methyl)phenol；2,4-dichloro-6-[3-(methylamino)propyliminomethyl]phenol
• CAS: 1051457-04-5
• 化学式: C₁₁H₁₄Cl₂N₂O
• 分子量: 261.151
• InChiKey: RFYDBIVQXPIFGY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  16
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  44.6
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  甲醇 、 2,4-dichloro-6-[(3-methylaminopropylimino)methyl]phenol 、 zinc dibromide 以 甲醇 、 水 为溶剂， 以53%的产率得到Zn(2,4-dichloro-6-[(3-methylaminopropylimino)methyl]phenol)Br2*CH3OH
  参考文献：
  名称：

  Synthesis, Characterization, and Crystal Structures of a Pair of Zinc(II) Complexes Derived from 2,4-dichloro-6-[(3-methylaminopropylimino)methyl]phenol

  摘要：

  The reaction of zinc(II) halides with Schiff base ligand 2,4-dichloro-6-[(3-methylaminopropylimino)methyl]phenol (HL) yields a pair of mononuclear complexes, [ZnLCl2](2)center dot CH3OH center dot H2O (1) and [ZnLBr2]center dot CH3OH (2). The structures of the complexes have been characterized by elemental analysis, IR spectra and single crystal X-ray diffraction. Complex (1) crystallizes in the P-1 space group with the unit cell a = 11.598(2), b = 11.972(2), c = 13.510(3) angstrom, alpha = 75.95(3)degrees, beta = 79.67(3)degrees, gamma = 67.80(3)degrees. Complex (2) crystallizes in the P2(1)2(1)2(1) space group with the unit cell a = 7.303(2), b = 8.135(2), c = 29.689(5)angstrom, alpha = beta = gamma = 90 degrees. Each Zn atom in the complexes is in a tetrahedral coordination.

  DOI：

  10.1080/15533170802255476
• 作为产物：
  描述：

  3-甲氨基丙胺 、 3,5-二氯水杨醛 以 乙醇 为溶剂， 反应 2.0h， 以yielding a yellow oil (1.45 gram, 100%)的产率得到2,4-dichloro-6-[(3-methylaminopropylimino)methyl]phenol
  参考文献：
  名称：

  METAL COMPLEXES OF SALAN-TYPE LIGANDS AND USES THEREOF AS CATALYSTS FOR POLYMERIZATION OF ALPHA-OLEFINS

  摘要：

  揭示了在α-烯烃聚合中使用包括第4族金属和Salan配体的预催化剂的均相催化体系的用途。Salan配体的特点是具有非对称的顺序二氨基骨架单元，预催化剂也可以是不具有对称元素的。所揭示的聚合产物为α-烯烃聚合物，例如高度具有定向性的聚丙烯。还揭示了新型的Salan配体及其与第4族金属的新配合物。

  公开号：

  US20130310529A1

文献信息

• Synthesis, Characterization and Crystal Structures of Four Dinuclear Schiff Base Nickel(II) and Copper(II) Complexes with Versatile Bridging Groups
  作者：Xiao‐Yang Qiu、Wei‐Sheng Liu、Hai‐Liang Zhu

  DOI：10.1002/zaac.200700132

  日期：2007.8

  Four novel Schiff base nickel(II) and copper(II) complexes, derived from the end-on (μ1,1-N3) azide, end-to-end (μ1,3-NCS) thiocyanate, or phenolate oxygen bridges, have been synthesized and their crystal structures determined by X-ray diffraction methods. They are the dinuclear double end-on azide-bridged [Ni2(L1)2(MeCN)2(μ1,1-N3)2]·MeOH (1), the dinuclear double end-on azide-bridged [Ni2(L2)2(MeOH)2(μ1

  四种新型席夫碱镍 (II) 和铜 (II) 配合物，源自端对 (μ1,1-N3) 叠氮化物、端对端 (μ1,3-NCS) 硫氰酸盐或酚盐氧桥，具有合成并通过 X 射线衍射方法确定了它们的晶体结构。它们是双核双端叠氮化物桥接 [Ni2 (L1) 2 (MeCN) 2 (μ1,1-N3) 2] · MeOH (1)，双核双端叠氮化物桥接 [Ni2 (L2) 2 (MeOH) 2 (µ1,1-N3) 2] [Ni2 (L2) 2 (OH2) 2 (µ1,1-N3) 2] • MeOH (2)，双核端对端硫氰酸酯桥连[Cu2 (L3) 2 (μ1,3-NCS) 2] (3)，和双核双酚O-桥接[Cu2 (L4) 2 (NCS) 2] (4)，其中HL1、HL2、HL3和HL4是通过 3,5-二溴水杨醛与 N-乙基乙烷-1,2-二胺、3,5-二氯水杨醛与 N-甲基丙烷-1,3-二胺缩合获得的四个三齿席夫碱，3-溴-5-氯水杨醛与
• Synthesis, characterization and photocatalytic activity of a dinuclear thiocyanate bridged cadmium(II) Schiff base complex
  作者：Sumit Roy、Klaus Harms、Shouvik Chattopadhyay

  DOI：10.1016/j.poly.2016.10.008

  日期：2017.5

  A dinuclear centrosymmetric cadmium(II) Schiff base complex, [Cd-2(L)(2)(mu-1,3-SCN)(2)(CH3OH)(2)], HL= 2-(3-(methylamino)propyliminomethyl)-4,6-dichlorophenol} has been synthesized and characterized. X-ray crystallography has confirmed its structure. The complex crystallizes in monoclinic space group C2/c with cell dimensions, a = 26.161(1) angstrom, b = 8.9412(3) angstrom, c = 18.9687(8) A, beta =129.202(1)degrees. Extended supra-molecular assemblies were generated through weak non-covalent interactions. The application of the complex as a photocatalyst for the decomposition of organic dye in visible light has been explored. (C) 2016 Elsevier Ltd. All rights reserved.
• Syntheses and Crystal Structures of Two Isostructural Zinc(II) Complexes With Schiff-bases 2-Bromo-4-chloro-6-[(3-methylaminopropylimino)methyl]phenol and 2,4-Dichloro-6-[(3-methylaminopropylimino)methyl]phenol
  作者：De-Suo Yang、Hai-Yun Zhu

  DOI：10.1080/15533170802440680

  日期：2008.11.7

  Two new isostructural mononuclear zinc(II) complexes, [Zn(C11H14Cl2N2O)(NCS)(CH3COO)] and [Zn(C11H14BrClN2O) (NCS)(CH3COO)], have been synthesized from the Schiff-bases 2-bromo-4-chloro-6-[(3-methylaminopropylimino)methyl]phenol and 2,4-dichloro-6-[(3-methylaminopropylimino)methyl]phenol, respectively. Both complexes were characterized by elemental analysis, IR spectra and single-crystal X-ray diffraction. The Zn atom in each of the complexes is coordinated by one phenolic oxygen atom and one imine nitrogen atom of a Schiff-base ligand, one nitrogen atom of a thiocyanate anion, and one oxygen atom of an acetate ligand, giving a tetrahedral geometry.