Δ-[Os(2,2'-bipyridine)(2,2'-bipyridine(-))2] | 56977-16-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: Δ-[Os(2,2'-bipyridine)(2,2'-bipyridine(-))2]
• 英文别名: Osmium;2-pyridin-2-ylpyridine
• CAS: 56977-16-3
• 化学式: C₃₀H₂₄N₆Os
• 分子量: 658.761
• InChiKey: HHHLWOBIYWDCIB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.43
• 重原子数：
  37
• 可旋转键数：
  0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  77.3
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  Δ-[Os(2,2'-bipyridine)3][BF4]2 以 乙腈 为溶剂， 生成 Δ-[Os(2,2'-bipyridine)(2,2'-bipyridine(-))2]
  参考文献：
  名称：

  Absorption, Circular Dichroism, and Luminescence Spectroscopy of Electrogenerated Δ-[Ru(bipy)₃]^+/0/- and Δ-[Os(bipy)₃]^+/0/- (bipy = 2,2‘-Bipyridine)

  摘要：

  The electronic absorption and circular dichroism (CD) spectra of the complexes produced by the one, two, and three electron reduction of Delta-[Ru(bipy)(3)](2+) and Delta-[Os(bipy)(3)](2+) are reported. The CD spectra give unequivocal proof that the added electrons are localized on individual bipiridine ligands and thus that the complexes are correctly formulated [M(bipy)(2)(bipy(-))](+), [M(bipy)(bipy(-))(2)](0), and [M(bipy(-))(3)](-). The absorption spectra of the triply reduced species [M(bipy(-))(3)](-) (M = Ru, Os) are compared to those of the Fe-II and Ir-III analogs. The luminescence spectra of the two triply reduced complexes [Ru(bipy(-))(3)](-) and [Os(bipy(-))(3)](-). are also presented. The MLCT luminescence found in the parent complexes is completely quenched and is replaced by a weak luminescence attributed to the pi(10) --> pi(7) transition of the (coordinated) [bipy](-) ion.

  DOI：

  10.1021/ic951096e

文献信息

• Electronic absorption and circular dichroism spectra of Δ-[Os(bipy)2(bipy−)]+, Δ-[Os(bipy)(bipy−)2]0 and Δ-[Os(bipy−)3]−
  作者：Brian C Noble、Robert D Peacock

  DOI：10.1016/0584-8539(94)80182-7

  日期：1994.9

  The electronic absorption and circular dichroism spectra of the complexes produced by the one-, two- and three-electron reduction of DELTA-[os(bipy)3]2+ are reported for the first time. The spectra confirm that, as in the cases of the Fe(II) and Ru(II) analogues, the electrons are localised on the bipyridine ligand and the complexes are correctly formulated [Os(bipy)2(bipy-)]+, [Os(bipy)(bipy-)2]0 and [Os(bipy-)3]-. The absorption spectra of the series of fully reduced complexes [M(bipy-)3]-: M = Fe, Ru, Os are compared.