Zn(Bu(t)NPN(C6H2Bu(t)3-2,4,6))2 | 166264-17-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Zn(Bu(t)NPN(C6H2Bu(t)3-2,4,6))2
• 英文别名: zinc;tert-butyl-(2,4,6-tritert-butylphenyl)iminophosphanylazanide
• CAS: 166264-17-1
• 化学式: C₄₄H₇₆N₄P₂Zn
• 分子量: 788.452
• InChiKey: ADBFXNOXUUQXSB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  16.85
• 重原子数：
  51
• 可旋转键数：
  12
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  26.7
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2,4,6-tritert-butyl-N-tert-butyliminophosphanylaniline 、 Dimethylzinc 以 正己烷 、 甲苯 为溶剂， 以67%的产率得到Zn(Bu(t)NPN(C6H2Bu(t)3-2,4,6))2
  参考文献：
  名称：

  Synthesis and structure of bis(phosphaallyl) complexes with two-co-ordinate phosphorus

  摘要：

  The compound (2,4,6-But(3)C(6)H(2))N(H)PN(SiMe(3))P(Cl)N(C(6)H(2)Bu(3)(t)-2,4,6) was prepared and its crystal structure determined. It is one of the rare examples of non-symmetrically substituted cyclophosphazanes. A series of bis- and mono- phosphaallyl complexes [M{(Me(3)Si)NPN(C(6)H(2)Bu(3)(t)-2,4,6)}(2)] (M = Zn or Cd), [Zn(Bu(t)NPNBu(t))(2)], [Zn{(4-(PrC6H4)-C-i)NPN(C(6)H(2)Bu(3)(t)-2,4,6)}(2)]. [Zn{R'NPN(C(6)H(2)Bu(3)(t)-2,4,6)}(2)] (R' = Bu(t) or adamantyl) and [Zn{(2,4,6-Bu(3)(t)C(6)H(2))NPN(C(6)H(2)Bu(3)(t)-2,4,6)}Me] have been prepared from cyclic aminophosphazanes and aminoiminophosphanes. The structure of the spirocyclic bis(1,3-diaza-2-phosphaallyl)zinc complex [Zn(RNPNR')2(]) (R = R' = C6H3Pr2i-2,6) was determined.

  DOI：

  10.1039/dt9950001951