| 154048-63-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 154048-63-2
• 化学式: C₄₆H₃₆N₆O₂
• 分子量: 704.831
• InChiKey: VVLWEZDUWOLAQY-UHFFFAOYSA-N

物化性质

• 沸点：
  845.3±65.0 °C(predicted)
• 密度：
  1.22±0.1 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

反应信息

• 作为反应物：
  描述：

  硫酸氧钒水合物 、 以 乙醇 、 水 为溶剂， 以45%的产率得到
  参考文献：
  名称：

  OXOVANADIUM(IV) COMPLEXES OF BIOINORGANIC AND INDUSTRIAL RELEVANCE: SYNTHESIS AND CHARACTERIZATION OF SOME OXOVANADIUM(IV) COMPLEXES INVOLVING SCHIFF BASES DERIVED FROM BIOLOGICALLY ACTIVE 4-BENZOYL-3-METHYL-1-PHENYL-2-PYRAZOLIN-5-ONE AND CERTAIN AROMATIC AMINES

  摘要：

  Seven new oxovanadium(IV) complexes, formed by the interaction of vanadyl sulfate pentahydrate and the Schiff bases, viz., N-(4'-benzoylidene-3'-methyl-1'-phenyl-2'-pyrazolin-5'-one)-p-anisidine (HL1), N-(4'-benzoylidene-3methyl-l'-phenyl-2'-pyrazolin-5'-one)-in-phenitidine (HL2), N-(4'-benzoylidene-3-methyl-1'-phenyl-2-pyrazolin-5-one)3 p-toluidine (HL), N,N-(4'-benzoylidene-3'-methyl-1'-phenyl- 4) 2'-pyrazolin-5'-one)-o-phenylenediamine (H,L, N,N-(4'-benzoylidene-3-methyl-1'-phenyl-2-pyrazolin-5'-one)-in-phenylenediamine (H2L5), N,N-(4'-benzoylidene-3-methyl-1'-phenyl-2'-pyrazolin-5'-one)-p-phenylenediamine (H2L6) and N,N-(4'-benzoylidene-3'-methyl-1'-phenyl-2'-pyrazolin-5'-one) -benzidine (H2L7) in aqueous-ethanol, are described. The resulting complexes were characterized by elemental analyses, molar conductances, magnetic and decomposition temperature measurements, electron spin resonance, IR and electronic spectral studies. They have the compositions, [VO(L')(2)(H2O)], where HL'=HL1, HL2 or HL3, [VO(L") (H2O)], where H2L"=H2L4 or H2L5 and [{VO(H2O) (OH)}(2)(L"')], where H2L"' = H2L6 or H2L7. The compounds [{VO(H2O)(OH)}(2)(L-6)] and [{VO(H2O)(OH)}(2)(L-7)] were found to show subnormal magnetic moments. Suitable structures have been proposed for these complexes.

  DOI：

  10.1081/sim-120003205