[(1,1'-bis(bis(dimethylamino)phosphino)ferrocene)dichloroplatinum] | 1264216-28-5

• 英文名称: [(1,1'-bis(bis(dimethylamino)phosphino)ferrocene)dichloroplatinum]
• 英文别名: [PtCl2(dmapf)]
• CAS: 1264216-28-5
• 化学式: C₁₈H₃₂Cl₂FeN₄P₂Pt
• 分子量: 688.259
• InChiKey: FRMQKEXNSIKLTH-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  bis(benzonitrile)dichloroplatinum(II) 、 1,1′-dilithioferrocene 、 双(二甲基氨)氯膦 以 四氢呋喃 为溶剂， 以5%的产率得到[(1,1'-bis(bis(dimethylamino)phosphino)ferrocene)dichloroplatinum]
  参考文献：
  名称：

  Bis(dialkylaminophosphino)ferrocenes: Reactivity and electrochemistry

  摘要：

  New compounds containing the 1,1'-bis(dialkylaminophosphino)ferrocene ligands 1,1'-bis(dimethylaminophosphino) ferrocene (dmapf) and 1,1'-bis(diethylaminophosphino)ferrocene (deapf) were prepared and characterized by NMR. The oxidative electrochemistries of these compounds were examined in methylene chloride. The transition metal compounds MnCl2(P-P) (M = Pd or Pt, n = 1, P-P = dmapf or deapf; M = Au, n = 2, P-P = dmapf) displayed one-electron, Nernstian waves. The corresponding selenides were prepared and the oxidative electrochemistries, along with those of the previously prepared 1,1'-bis(alkylaminophosphine sulfide) ferrocene, were examined. The sulfides displayed one-electron, Nernstian oxidations. The selenides displayed electrochemically irreversible two-electron waves. The X-ray structures of the sulfides and selenides as well as that of the transition metal compounds [(AuCl)(2)(dmapf)] and [PtCl2(dmapf)] were determined. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.06.061