5,11,17,23,29,35-hexa(tert-butyl)-37,38,39,40,41,42-hexamethoxy-2,8,14,20,26,32-hexa(2-propanonyl)calix[6]arene | 1263217-59-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 5,11,17,23,29,35-hexa(tert-butyl)-37,38,39,40,41,42-hexamethoxy-2,8,14,20,26,32-hexa(2-propanonyl)calix[6]arene
• CAS: 1263217-59-9
• 化学式: C₉₀H₁₂₀O₁₂
• 分子量: 1393.94
• InChiKey: YIZJMIZHGCZMKA-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  3-[5,11,17,23,29,35-Hexatert-butyl-8,14,20,26,32-pentakis(2,4-dioxopentan-3-yl)-37,38,39,40,41,42-hexamethoxy-2-heptacyclo[31.3.1.13,7.19,13.115,19.121,25.127,31]dotetraconta-1(36),3,5,7(42),9,11,13(41),15,17,19(40),21(39),22,24,27(38),28,30,33(37),34-octadecaenyl]pentane-2,4-dione 在 sodium hydroxide 作用下， 以 甲醇 、 水 为溶剂， 反应 0.25h， 以48%的产率得到5,11,17,23,29,35-hexa(tert-butyl)-37,38,39,40,41,42-hexamethoxy-2,8,14,20,26,32-hexa(2-propanonyl)calix[6]arene
  参考文献：
  名称：

  Calix[6]arenes incorporating functionalised substituents at the methylene bridges

  摘要：

  The hexabromocalix[6]arene 5 reacts with p-tert-Bu-phenol, thymol and propargyl alcohol to afford the corresponding hexasubstituted methylene-functionalised calixarenes. The substituents at the bridges were further functionalised via acetylation or click chemistry. Reaction of the hexahydroxy derivative 10 with DAST afforded 11, a first example of a calixarene with all bridges monofluorinated.

  DOI：

  10.1080/10610278.2010.500728