Zn(monoacetylferrocene thiosemicarbazone(1-))2 | 1345893-48-2

• 英文名称: Zn(monoacetylferrocene thiosemicarbazone(1-))2
• CAS: 1345893-48-2；311817-36-4
• 化学式: C₂₆H₂₈Fe₂N₆S₂Zn
• 分子量: 665.765
• InChiKey: LOHXAOINTPTCQJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Zn(monoacetylferrocene thiosemicarbazone(1-))2 以 neat (no solvent, solid phase) 为溶剂， 生成 iron;sulfane;zinc
  参考文献：
  名称：

  Preparation of ternary metal chalcogenide (M1-FexS, M = Cd and Zn) nanocrystallites using single source precursors

  摘要：

  M1-xFexS (M - Cd, Zn) nanocrystallites were prepared by pyrolysis and solvothermal decomposition methods using [M(Aftscz)(2)] and [M(AftsczH)(2)Cl-2] (M = Cd, Zn and AftsczH = monoacetylferrocene thiosemicarbazone) as single source precursors. The M1-xFexS nanocrystallites were characterized by powder X-ray diffraction (XRD), transmission electron microscopy (TEM), energy dispersive X-ray analysis and UV-Visible spectroscopy. XRD patterns show that the Cd1-xFexS and Zn1-xFexS nanocrystallites prepared by pyrolysis and solvothermal decomposition routes have hexagonal phase. TEM images show presence of spherical and spherical plate-like morphology of M1-xFexS nanoparticles. M1-xFexS nanoparticles obtained by solvothermal decomposition in ethylene glycol are found to be capped with ethylene glycol as evident from IR spectra. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2011.07.001
• 作为产物：
  描述：

  1-acetylferrocenehydrazinecarbothioamide 、 zinc(II) acetate dihydrate 以 乙醇 为溶剂， 以62%的产率得到Zn(monoacetylferrocene thiosemicarbazone(1-))2
  参考文献：
  名称：

  Preparation of ternary metal chalcogenide (M1-FexS, M = Cd and Zn) nanocrystallites using single source precursors

  摘要：

  M1-xFexS (M - Cd, Zn) nanocrystallites were prepared by pyrolysis and solvothermal decomposition methods using [M(Aftscz)(2)] and [M(AftsczH)(2)Cl-2] (M = Cd, Zn and AftsczH = monoacetylferrocene thiosemicarbazone) as single source precursors. The M1-xFexS nanocrystallites were characterized by powder X-ray diffraction (XRD), transmission electron microscopy (TEM), energy dispersive X-ray analysis and UV-Visible spectroscopy. XRD patterns show that the Cd1-xFexS and Zn1-xFexS nanocrystallites prepared by pyrolysis and solvothermal decomposition routes have hexagonal phase. TEM images show presence of spherical and spherical plate-like morphology of M1-xFexS nanoparticles. M1-xFexS nanoparticles obtained by solvothermal decomposition in ethylene glycol are found to be capped with ethylene glycol as evident from IR spectra. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2011.07.001