O-[Ru(2,2'-bipyridine)(2,2'-biquinoline)(2-methylsulfinylbenzoate)](1+) | 1227377-39-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: O-[Ru(2,2'-bipyridine)(2,2'-biquinoline)(2-methylsulfinylbenzoate)](1+)
• CAS: 1227377-39-0
• 化学式: C₈H₇O₃S*C₁₀H₈N₂*C₁₈H₁₂N₂*Ru
• 分子量: 696.771
• InChiKey: QQOCRMDZQHDCHB-XADMQAQGSA-M

反应信息

• 作为反应物：
  描述：

  O-[Ru(2,2'-bipyridine)(2,2'-biquinoline)(2-methylsulfinylbenzoate)](1+) 以 further solvent(s) 为溶剂， 生成 S-[Ru(2,2'-bipyridine)(2,2'-biquinoline)(2-methylsulfinylbenzoate)](1+)
  参考文献：
  名称：

  Solvent Effects on Isomerization in a Ruthenium Sulfoxide Complex

  摘要：

  We report the structure, electrochemistry, and isomerization kinetics for [Ru(bpy)(biq)(OSO)](PF6), where bpy is 2,2'-bipyridine, biq is 2,2'-biquinoline, and OSO is 2-methylsulfinylbenzoate. UV visible and infrared data are suggestive of intramolecular S -> O and O -> S isomerization of the sulfoxide. Cyclic voltammetry reveals evidence for isomerization triggered by oxidation and reduction. Of particular note is the variation of the S -> O isomerization rate constant in different solvents. The rates were found to be 3.2 (+/- 0.4) s(-1) in propylene carbonate, 0.80 (+/- 0.03) s(-1) in acetonitrile, and 0.26 (+/- 0.01) s(-1) dichloromethane.

  DOI：

  10.1021/ic902047f
• 作为产物：
  描述：

  S-[Ru(2,2'-bipyridine)(2,2'-biquinoline)(2-methylsulfinylbenzoate)](1+) 以 further solvent(s) 为溶剂， 生成 O-[Ru(2,2'-bipyridine)(2,2'-biquinoline)(2-methylsulfinylbenzoate)](1+)
  参考文献：
  名称：

  Solvent Effects on Isomerization in a Ruthenium Sulfoxide Complex

  摘要：

  We report the structure, electrochemistry, and isomerization kinetics for [Ru(bpy)(biq)(OSO)](PF6), where bpy is 2,2'-bipyridine, biq is 2,2'-biquinoline, and OSO is 2-methylsulfinylbenzoate. UV visible and infrared data are suggestive of intramolecular S -> O and O -> S isomerization of the sulfoxide. Cyclic voltammetry reveals evidence for isomerization triggered by oxidation and reduction. Of particular note is the variation of the S -> O isomerization rate constant in different solvents. The rates were found to be 3.2 (+/- 0.4) s(-1) in propylene carbonate, 0.80 (+/- 0.03) s(-1) in acetonitrile, and 0.26 (+/- 0.01) s(-1) dichloromethane.

  DOI：

  10.1021/ic902047f