Benzylamin-Phenol-Komplex | 16845-53-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Benzylamin-Phenol-Komplex
• 英文别名: Phenol;phenylmethanamine
• CAS: 16845-53-7
• 化学式: C₆H₆O*C₇H₉N
• 分子量: 201.268
• InChiKey: KJYFVDKSSVPAPE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.54
• 重原子数：
  15
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  46.2
• 氢给体数：
  2
• 氢受体数：
  2

文献信息

• Novel Catalyst Compositions and Methods of Making and Using Same
  申请人：CHEVRON PHILLIPS CHEMICAL COMPANY LP

  公开号：US20140121343A1

  公开（公告）日：2014-05-01

  An imine phenol compound having Structure I: wherein O and N represent oxygen and nitrogen respectively; R comprises a halogen, a hydrocarbyl group, or a substituted hydrocarbyl group; R 2 and R 3 can each independently be hydrogen, a halogen, a hydrocarbyl group, or a substituted hydrocarbyl group; and Q is a donor group. A method comprising contacting a catalyst composition with a monomer under conditions suitable for the formation of a polymer wherein the catalyst composition comprises a metal salt complex of an imine (bis)phenolate compound, a solid oxide, and an optional metal alkyl and wherein the metal salt complex of an imine (bis)phenolate compound has Structure XIV where M is titanium, zirconium, or hafnium; OE t2 is ethoxide, R comprises a halogen, a hydrocarbyl group, or a substituted hydrocarbyl group; and R 2 comprises hydrogen, a halogen, a hydrocarbyl group, or a substituted hydrocarbyl group.

  具有结构I的亚胺酚化合物，其中O和N分别代表氧和氮；R包括卤素、烃基团或取代烃基团；R2和R3可以分别独立地是氢、卤素、烃基团或取代烃基团；Q是给体基团。一种方法包括将催化剂组合物与单体在适合形成聚合物的条件下接触，其中催化剂组合物包括亚胺（双）酚酸盐化合物的金属盐络合物、固体氧化物和可选的金属烷基，其中亚胺（双）酚酸盐化合物的金属盐络合物具有结构XIV，其中M为钛、锆或铪；OEt2为乙氧基，R包括卤素、烃基团或取代烃基团；R2包括氢、卤素、烃基团或取代烃基团。
• Process for preparing N-alkylaminophenols and N,N-dialkylaminophenols
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0427572A1

  公开（公告）日：1991-05-15

  To prepare an N-alkylaminophenol an aminophenol is subjected to reductive alkylation with an aliphatic or cyclic aldehyde or ketone in the presence of an organic solvent (e.g. an alcohol), hydrogen, and a reduction catalyst comprising platinum or palladium and at least one metal element selected from the IB, IIB, IVB, VB and VIB group of the Periodic Table, either supported on activated carbon, or which has been contact treated with a solution containing at least one said metal element. The preferred amount of the metal in the catalyst is 0.001 to 0.5 part by weight. The preferred amount of the catalyst is 0.0001 to 0.02 part by weight as Pt or Pd per part of the aminophenol. The catalyst can be recovered and reused. The preparation of the catalyst is described.

  为制备 N-烷基氨基苯酚，氨基苯酚在有机溶剂（如醇）、氢和还原催化剂的存在下，与脂族或环族醛或酮进行还原烷基化反应，还原催化剂由铂或钯和至少一种选自元素周期表 IB、IIB、IVB、VB 和 VIB 族的金属元素组成。 按重量计，催化剂中的金属量最好为 0.001 至 0.5 份。催化剂的优选量为每份氨基苯酚含 0.0001 至 0.02 份重量的铂或钯。 催化剂可以回收和重复使用。 催化剂的制备方法已作说明。
• Process for preparing N-alkyl-substituted aminophenols
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0411817A2

  公开（公告）日：1991-02-06

  A process for preparing an N-alkyl-substituted amino­phenol comprises continuously feeding an aldehyde or a ketone to a reaction system containing an organic solvent, e.g., methanol or ethanol, a catalyst for reduction (e.g., Pt or Pd), hydrogen, and an aminophenol to conduct a reductive alkylation reaction, wherein said reductive alkylation react­ion is carried our while continuously adding an organic carboxylic acid (e.g. a mono or di-carboxylic or hydroxy­carboxylic acid of up to 8 carbon atoms), in amount of 0.05 to 5 wt % of the aminophenol, diluted with said solvent. The aldehyde or ketone can first be added to the system apart from the acid, which is added continuously when hydrogen absorption has begun. The process attains a high yield even when the catalyst is repeatedly reused, and does not cause corrosion of equipment.

  一种制备 N-烷基取代氨基苯酚的工艺包括：向含有有机溶剂（如甲醇或乙醇）、还原催化剂（如铂或钯）、氢和氨基苯酚的反应体系中连续加入醛或酮，以进行还原烷基化反应、其中，在进行还原烷基化反应的同时，不断加入用所述溶剂稀释的有机羧酸（例如，碳原子数不超过 8 的单羧酸或二羧酸或羟基羧酸），其用量为氨基苯酚的 0.05 至 5 wt %。醛或酮可以先与酸分开加入体系中，当开始吸氢时再继续加入。 即使催化剂重复使用，该工艺也能达到很高的产量，而且不会对设备造成腐蚀。
• Low-sulphur odorants for liquid gas
  申请人：Mansfeld Gerd

  公开号：US20060009372A1

  公开（公告）日：2006-01-12

  The present invention relates to acrylic acid alkyl ester mixtures containing a low proportion of sulphurous compounds, the use of these to odorize liquid gas, a method for odorizing liquid gas and liquid gas containing these mixtures.

  本发明涉及含有低比例亚硫化合物的丙烯酸烷基酯混合物、使用这些混合物对液态气体进行加臭、对液态气体进行加臭的方法以及含有这些混合物的液态气体。
• NOVEL CATALYST COMPOSITIONS AND METHOD OF MAKING AND USING THE SAME FOR THE POLYMERIZSATION OF OLEFIN, HIGH DENSITY POLYETHYLENE
  申请人：Chevron Phillips Chemical Company LP

  公开号：EP2912076A1

  公开（公告）日：2015-09-02