(Z)-甲基苯基二氮烯 | 34000-44-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: (Z)-甲基苯基二氮烯
• 英文名称: (Z)-Methylphenyldiazen
• 英文别名: cis-Phenylazomethan；syn-Methylphenyldiimid
• CAS: 34000-44-7
• 化学式: C₇H₈N₂
• 分子量: 120.154
• InChiKey: SHHIUWFOBYRJAM-HJWRWDBZSA-N

物化性质

• 沸点：
  156.6±9.0 °C(Predicted)
• 密度：
  0.96±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  9.0
• 可旋转键数：
  1.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  24.72
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  1-acetyl-1-methyl-2-phenylhydrazine 在 phosphate buffer 、 potassium hexacyanoferrate(III) 作用下， 以 水 为溶剂， 反应 2.0h， 以35.5%的产率得到(Z)-甲基苯基二氮烯
  参考文献：
  名称：

  Bresser; Weber, Pharmazie, 1996, vol. 51, # 7, p. 470 - 476

  摘要：

  DOI：

文献信息

• [EN] FUNCTIONALIZED AND MULTIVARIATE BTB-BASED METAL ORGANIC FRAMEWORKS<br/>[FR] STRUCTURES DE SQUELETTES ORGANOMÉTALLIQUES À BASE DE BTB À PLUSIEURS VARIABLES ET FONCTIONNALISÉS
  申请人：UNIV CALIFORNIA

  公开号：WO2015157239A1

  公开（公告）日：2015-10-15

  The disclosure provides for metal organic frameworks (MOFs) which comprise a plurality of SBUs linked together by functionalized or multivariate BTB-based linking ligands. The disclosure further provides for the use of these MOFs in variety of applications, including for gas separation, gas storage, catalysis, and separation of compounds or bioproducts.

  该披露提供了一种金属有机框架（MOFs），其包括通过功能化或多元BTB基连接配体连接在一起的多个SBUs。该披露进一步提供了这些MOFs在各种应用中的使用，包括用于气体分离、气体储存、催化和化合物或生物产品的分离。
• Detecting targets using mass tags and mass spectrometry
  申请人：Ventana Medical Systems, Inc.

  公开号：US10883999B2

  公开（公告）日：2021-01-05

  Particular disclosed embodiments disclosed herein concern using a one or more various mass tags, which can be specifically deposited at targets through direct or indirect enzymatic-catalyzed transformation, to provide a method for identifying targets in tissue samples. The mass tags may be labeled with stable isotopes to produce mass tags having the same chemical structure but different masses. Mass codes produced by ionizing the mass tags are detected and/or quantified using mass spectrometry. The method can be used for multiplexed detection of multiple targets in a particular sample. In some embodiments, a map divided into sections representing sections of the tissue sample may be prepared, with the map sections including data corresponding to quantification data wherein the size of a mass peak is determined and correlated with the amount of a target for the corresponding tissue sample section.

  本文所公开的具体实施方案涉及使用一种或多种不同的质量标记，通过直接或间接的酶催化转化特异性地沉积在靶标上，从而提供一种识别组织样本中靶标的方法。质量标签可以用稳定同位素标记，以产生化学结构相同但质量不同的质量标签。通过电离质量标签产生的质量代码可使用质谱法进行检测和/或定量。该方法可用于特定样品中多个目标的多重检测。在某些实施方案中，可制备代表组织样本切片的图谱，图谱切片包括与定量数据相对应的数据，其中质量峰的大小被确定并与相应组织样本切片的靶标量相关联。
• Reactive navy to black dye composition and dye product thereof
  申请人：Zhejiang Keyong Chemical Co., Ltd.

  公开号：US10954392B2

  公开（公告）日：2021-03-23

  A reactive navy to black dye composition comprises component A and component B, wherein component A is selected from one or more compounds of formula (I), component B is selected from one or more compounds of formula (II); D1 and D2 are each independently a group represented by the following formula (a) or (b) or (c); R1-R12 are each independently selected from the group consisting of H, linear or branched C1˜C4 alkyl, C1˜C4 alkoxy and sulfo; m, n=0-3, and every R3 is each independently selected from the group consisting of amino, sulfo, ureido, C1˜C4 alkanoylamino, C1˜C4 alkoxy and C1˜C4 alkyl, every R6 is each independently selected from the group consisting of amino, hydroxyl and sulfo; X1-X3 are each independently selected from the group consisting of H, C1˜C4 alkyl, C1˜C4 alkoxy, —SO2Y1, —NHCO(CH2)pSO2Y2 and —CONH(CH2)qSO2Y3, and at least one of D1 and D2 contains a fiber-reactive group, p, q=1-3, and Y1˜Y5 are each independently selected from the group consisting of —CH═CH2, —C2H4OSO3H and —CH2CH2Cl. A reactive navy to black dye product comprising the dye composition, has the properties of good washing fastness, high degree of fixation and dye-uptake, good build-up, clear remanent dyeing liquor, and the like.

  一种活性海军蓝至黑色染料组合物包括组分A和组分B，其中组分A选自式(I)的一种或多种化合物，组分B选自式(II)的一种或多种化合物；D1和D2各自独立地为下式(a)或(b)或(c)所代表的基团；R1-R12各自独立地选自H、线性或支链C1˜C4烷基、C1˜C4烷氧基和磺基组成的组；m、n=0-3 和每个 R3 各自独立地选自由氨基、磺基、脲基、C1˜C4 烷酰氨基、C1˜C4 烷氧基和 C1˜C4 烷基组成的组，每个 R6 各自独立地选自由氨基、羟基和磺基组成的组；X1-X3 各自独立地选自由 H、C1˜C4 烷基、C1˜C4 烷氧基、-SO2Y1、-NHCO(CH2)pSO2Y2 和-CONH( )qSO2Y3 组成的组，且 D1 和 D2 中至少有一个含有纤维活性基团，p、q=1-3，以及 Y1˜Y5 各自独立地选自由 -CH═ 、-C2H4OSO3H 和 - Cl 组成的组。包含该染料组合物的活性海军蓝至黑色染料产品具有良好的耐洗牢度、高固着度和上染性、良好的上染性、清澈的残留染液等特性。
• Reactive dye compound and preparation method and application thereof
  申请人：Zhejiang Keyong Chemical Co., Ltd.

  公开号：US11370921B2

  公开（公告）日：2022-06-28

  A reactive dye compound and preparation method and application for printing and dyeing of cellulosic fibers, polyamide fibers and fabrics thereof. Formula (I) is the dye compound structure where D1 and D2 are each independently the group of the following formula (a) or (b) or (c), and D1 and D2 are not simultaneously selected from the following formula (a). R1, R2, R4, R5, R7 and R8 are each independently H, linear or branched C1˜C4 alkyl, C1˜C4 alkoxy or sulfo; m=0-3. Each R3 is independently selected from amino, sulfo, ureido, C1˜C4 alkyl, C1˜C4 alkanoylamino or C1˜C4 alkoxy, n=0-3, and each R6 is independently selected from hydroxyl, amino and sulfo. X1, X2 and X3 are each independently H, C1˜C4 alkyl, C1˜C4 alkoxy, —SO2Y1, —NHCO(CH2)pSO2Y2 or —CONH(CH2)qSO2Y3, and at least one of D1 and D2 contains a fiber-reactive group. Y1˜Y3 are each independently —CH═CH2, —C2H4OSO3H or —CH2CH2Cl, p=1-3, and q=1-3.

  一种活性染料化合物及其制备方法和应用，用于纤维素纤维、聚酰胺纤维及其织物的印染。式（I）为染料化合物结构，其中 D1 和 D2 各自独立地为下式（a）或（b）或（c）的基团，且 D1 和 D2 不同时选自下式（a）。R1、R2、R4、R5、R7 和 R8 各自独立地为 H、直链或支链 C1˜C4烷基、C1˜C4 烷氧基或磺基；m=0-3。每个 R3 独立地选自氨基、磺基、脲基、C1˜C4 烷基、C1˜C4 烷酰氨基或 C1˜C4 烷氧基，n=0-3，每个 R6 独立地选自羟基、氨基和磺基。X1、X2 和 X3 各自独立地为 H、C1˜C4 烷基、C1˜C4 烷氧基、-SO2Y1、-NHCO(CH2)pSO2Y2 或 -CONH( )qSO2Y3，且 D1 和 D2 中至少有一个含有纤维反应基团。Y1˜Y3各自独立地为-CH═ 、-C2H4OSO3H或- Cl，p=1-3和q=1-3。
• DETECTING TARGETS USING MASS TAGS AND MASS SPECTROMETRY
  申请人：Hong Rui

  公开号：US20130122516A1

  公开（公告）日：2013-05-16

  Particular disclosed embodiments disclosed herein concern using a one or more various mass tags, which can be specifically deposited at targets through direct or indirect enzymatic-catalyzed transformation, to provide a method for identifying targets in tissue samples. The mass tags may be labeled with stable isotopes to produce mass tags having the same chemical structure but different masses. Mass codes produced by ionizing the mass tags are detected and/or quantified using mass spectrometry. The method can be used for multiplexed detection of multiple targets in a particular sample. In some embodiments, a map divided into sections representing sections of the tissue sample may be prepared, with the map sections including data corresponding to quantification data wherein the size of a mass peak is determined and correlated with the amount of a target for the corresponding tissue sample section.