bis(((diphenylmethylene)amino)diphenyl-l5-phosphaneyl)(((trifluoromethyl)sulfonyl)oxy)silver | 573965-10-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(((diphenylmethylene)amino)diphenyl-l5-phosphaneyl)(((trifluoromethyl)sulfonyl)oxy)silver
• CAS: 573965-10-3
• 化学式: C₅₁H₄₀AgF₃N₂O₃P₂S
• 分子量: 987.767
• InChiKey: IUVCITZFDKNBOI-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  silver trifluoromethanesulfonate 、 <(Diphenylmethyliden)amino>diphenylphosphin 以 乙醚 为溶剂， 以77%的产率得到bis(((diphenylmethylene)amino)diphenyl-l5-phosphaneyl)(((trifluoromethyl)sulfonyl)oxy)silver
  参考文献：
  名称：

  Structural characterization of silver(I) complexes of diphenylmethanimine and (diphenylmethyleneamino)diphenylphosphine

  摘要：

  The reaction of NH = CPH2 with the silver species [AgX(PPh3)] (X = ClO4, SO3CF3) affords the derivatives [Ag(PPh3)(NH = CPh2)]X. Complexes [Ag(Ph2PN = CPh2)(2)]X (X = Cl, ClO4, SO3CF3) have been obtained from Ph2PN = CPh2 and the corresponding silver salt AgX. X-ray diffraction studies have been carried out for four of the derivatives. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)01438-x