1-tert-butyl-2-chloro-5H-azaborole | 410075-90-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 硼酸衍生物
• 英文名称: 1-tert-butyl-2-chloro-5H-azaborole
• CAS: 410075-90-0
• 化学式: C₇H₁₃BClN
• 分子量: 157.451
• InChiKey: LRGLSYQIOAGOPW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.92
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  potassium diphenylphosphine 、 1-tert-butyl-2-chloro-5H-azaborole 以 not given 为溶剂， 生成 (1-tert-butyl-5H-azaborol-2-yl)-diphenylphosphane
  参考文献：
  名称：

  The First General Method for the Synthesis of Transition-Metal π Complexes of an Electronically Diverse Family of 1,2-Azaborolyls

  摘要：

  A general method for the synthesis of new families of transition-metal-free 1,2-azaborolides'(3) has been developed, based on a readily available precursor (1). These azaborolides react with a variety of transition-metal electrophiles to produce an unprecedented array of eta(5)-azaborolyl adducts (4) (substituents bound to boron: nitrogen, oxygen, hydrogen, carbon, and phosphorus).

  DOI：

  10.1021/om020533b
• 作为产物：
  描述：

  1-tert.Butyl-2,2-dimethyl-Δ³-1,2-azastannolin 在 三氯化硼 作用下， 生成 1-tert-butyl-2-chloro-5H-azaborole
  参考文献：
  名称：

  1,2-Azaborolyls, Isoelectronic Analogues of the Ubiquitous Cyclopentadienyl Ligand: Synthesis of B-Heteroatom-Substituted 1,2-Azaborolyl Complexes and an Assessment of Their Electronic Features

  摘要：

  DOI：

  10.1002/1521-3773(20020104)41:1<174::aid-anie174>3.0.co;2-7

文献信息

• 1,2-Azaborolyls, Isoelectronic Analogues of the Ubiquitous Cyclopentadienyl Ligand: Synthesis of B-Heteroatom-Substituted 1,2-Azaborolyl Complexes and an Assessment of Their Electronic Features
  作者：Shih-Yuan Liu、Michael M.-C. Lo、Gregory C. Fu

  DOI：10.1002/1521-3773(20020104)41:1<174::aid-anie174>3.0.co;2-7

  日期：2002.1.4
• The First General Method for the Synthesis of Transition-Metal π Complexes of an Electronically Diverse Family of 1,2-Azaborolyls
  作者：Shih-Yuan Liu、Ivory D. Hills、Gregory C. Fu

  DOI：10.1021/om020533b

  日期：2002.10.1

  A general method for the synthesis of new families of transition-metal-free 1,2-azaborolides'(3) has been developed, based on a readily available precursor (1). These azaborolides react with a variety of transition-metal electrophiles to produce an unprecedented array of eta(5)-azaborolyl adducts (4) (substituents bound to boron: nitrogen, oxygen, hydrogen, carbon, and phosphorus).