[Pt(Me)(1,2-bis(diphenylphosphino)ethane)(η1-CH(PPh3)(COOEt))]BF4 | 365222-31-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Pt(Me)(1,2-bis(diphenylphosphino)ethane)(η1-CH(PPh3)(COOEt))]BF4
• 英文别名: carbanide;2-diphenylphosphanylethyl(diphenyl)phosphane;(2-ethoxy-2-oxoethyl)-triphenylphosphanium;platinum(2+);tetrafluoroborate
• CAS: 365222-31-7
• 化学式: BF₄*C₄₉H₄₈O₂P₃Pt
• 分子量: 1043.72
• InChiKey: VJQBVBKMXGRXAS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  乙醇 、 carbanide;2-diphenylphosphanylethyl(diphenyl)phosphane;platinum(2+);2-(triphenyl-λ5-phosphanylidene)ethenone;tetrafluoroborate 以 not given 为溶剂， 以0%的产率得到[Pt(Me)(1,2-bis(diphenylphosphino)ethane)(η1-CH(PPh3)(COOEt))]BF4
  参考文献：
  名称：

  Synthesis, characterization and crystal structure of [Pt(Me)(dppe){η1-CH(PPh3)(COOEt)}]BF4. An example of overcrowded molecule and correlated properties

  摘要：

  The complex [Pt(Me)(dppe){eta (1)-CH(PPh3)(COOEt)}]BF4 has been synthesized and characterized spectroscopically and structurally. It crystallizes in the space group P2(1)/n, with lattice constants a = 14.525(3) Angstrom, b = 14.931(3) Angstrom, c = 21.921(4) Angstrom, beta = 103.47(3)degrees. The X-ray analysis revealed a particularly overcrowded molecular structure containing high stereochemical constraints. The structural features account for specific chemical and physical properties of this compound, thus representing an interesting example of applied crystallography. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)00864-6