(octaethylporphyrinato)rhodium(II)*CHO | 79666-16-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (octaethylporphyrinato)rhodium(II)*CHO
• CAS: 79666-16-3
• 化学式: C₃₇H₄₅N₄ORh
• 分子量: 664.696
• InChiKey: NEBVVSAPMCTOCR-YAJYDHHFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (octaethylporphyrinato)rhodium(II)*CHO 以 乙醇 、 二氯甲烷-D2 为溶剂， 生成 (2,3,7,8,12,13,17,18-octaethylporphyrinato)rhodium(III) chloride
  参考文献：
  名称：

  Generation of an (alkoxycarbonyl)rhodium complex in an alcohol analog of the water-gas shift reaction

  摘要：

  (Octaethylporphyrinato)rhodium(II) dimer ((OEPRh)2, 1) reacts with CO and ethanol in CH2Cl2 to give (octaethylporphyrinato)rhodium(III) chloride (5), (ethoxycarbonyl)(octaethylporphyrinato) rhodium(III) (OEPRh(CO)OEt, 6), and formyl(octaethylporphyrinato)rhodium-(III) (2). The structure of 6 was clarified by X-ray diffraction analysis. Complex 6 crystallized in the monoclinic space group P2(1)/n (No. 14) with a = 14.581 (1) angstrom, b = 14.181 (2) angstrom, c = 17.4530 (9) angstrom, V = 3608.8 (9) angstrom3, Z = 4, R = 0.046, R(w) = 0.051, and T = 293 K for 415 parameters and 4864 reflections. The H-1 and C-13 spectral properties of 2 and 6 in CD2Cl2 were determined and the behaviors of 1, 2, (octaethylporphyrinato)rhodium(III) hydride (3), and 6 in CH2Cl2 solvent were examined. Photolysis of 2 in CH2Cl2 at 300 nm afforded (octaethylporphyrinato)rhodium-(III) chloride. Treatment of OEPCoNa with acetic anhydride in ethylene glycol dimethyl ether afforded acetyl(octaethylporphyrinato)cobalt(III) and an analogous experiment with acetic formic anhydride generated an acyl(octaethylporphyrinato)cobalt(III) complex.

  DOI：

  10.1021/om00028a033
• 作为产物：
  描述：

  octaethylporphyrinatorhodium(II) dimer 在 CO 、 H₂O 作用下， 以 氘代苯 为溶剂， 以>99的产率得到(octaethylporphyrinato)rhodium(II)*CHO
  参考文献：
  名称：

  Reactions of carbon monoxide and alkyl isonitriles with rhodium octaethylporphyrin species: metallo formyl and formimidoyl complexes

  摘要：

  DOI：

  10.1021/ja00365a062

文献信息

• Reactivity of rhodium and iridium octaethylporphyrin hydrides toward carbon monoxide: thermodynamic studies of the rhodium formyl and iridium hydrido carbonyl complexes
  作者：Maria D. Farnos、Bruce A. Woods、Bradford B. Wayland

  DOI：10.1021/ja00273a019

  日期：1986.6

  Reaction du monoxyde de carbone avec Ir(OEP)H et Rh(OEP)H qui fournit respectivement Ir(OEP)(H)(CO) et Rh(OEP)(CHO). Etudes thermodynamiques de ces reactions

  反应二一氧化碳 avec Ir(OEP)H 和 Rh(OEP)H 分别是 Ir(OEP)(H)(CO) 和 Rh(OEP)(CHO)。热力学反应练习曲
• Insertion and oxidative addition reactions of rhodium porphyrin complexes. Novel free radical chain mechanisms
  作者：Ralph S. Paonessa、Nicholas C. Thomas、Jack Halpern

  DOI：10.1021/ja00300a044

  日期：1985.7

  Cinetique des reactions de Rh 2 (OEP) 2 et (OEP)RhH avec le styrene. Mecanisme des reactions

  Cinetique des reaction de Rh 2 (OEP) 2 et (OEP)RhH avec le 苯乙烯。反应机制
• Observation of a neutral metallo-formyl complex formed by the reaction of rhodium octaethylporphyrin hydride with carbon monoxide
  作者：Bradford B. Wayland、Bruce A. Woods

  DOI：10.1039/c39810000700

  日期：——

  Rhodium octaethylporphyrin hydride, RhOEP-(H)(OEP = octaethylporphyrin),m reacts with carbon monoxide to form a neutral metallo-formyl complex.

  八乙基卟啉铑氢化物RhOEP-（H）（OEP =八乙基卟啉）m与一氧化碳反应形成中性的金属甲酰络合物。
• Preparation of heterobimetallic compounds containing octaethylporphyrinrhodium and their reactions with hydrogen and carbon monoxide
  作者：H.William Bosch、Bradford B. Wayland

  DOI：10.1016/s0022-328x(00)99352-5

  日期：1986.12

  Octaethylporphyrinrhodium dimer ([Rh(OEP)]2) reacts with a series of transition metal dimers (M′M′; M′ = Mn(CO)5; Mo(CO)3Cp; Ru(CO)2C5Me5) to form metalmetal bonded heterobimetallic compounds ((OEP)RhM′). The heterobimetallic compounds reported in this paper react with H2 and CO to produce M′H and equilibrium quantities of Rh(OEP)(H) and Rh(OEP)(CHO).

  八乙基卟啉铑二聚体（[Rh（OEP）] 2）与一系列过渡金属二聚体（M'M'; M'= Mn（CO）5 ; Mo（CO）3 Cp; Ru（CO）2 C 5 Me 5）形成金属金属键合的异双金属化合物（（OEP）RhM'）。本文报道的杂双金属化合物与H 2和CO反应生成M'H以及平衡量的Rh（OEP）（H）和Rh（OEP）（CHO）。
• Wayland, Bradford B.; Balkus Jr., Kenneth J.; Farnos, Maria D., Organometallics, 1989, vol. 8, # 4, p. 950 - 955
  作者：Wayland, Bradford B.、Balkus Jr., Kenneth J.、Farnos, Maria D.

  DOI：——

  日期：——