{RhRe(CO)4(bis(diphenylphosphino)methane)2} | 126925-93-7

• 英文名称: {RhRe(CO)4(bis(diphenylphosphino)methane)2}
• CAS: 126925-93-7
• 化学式: C₅₄H₄₄O₄P₄ReRh
• 分子量: 1169.95
• InChiKey: BWELNZKYSVJOTE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  {RhRe(CO)4(bis(diphenylphosphino)methane)2} 在 H₂S 作用下， 以 四氢呋喃 为溶剂， 以95%的产率得到{RhRe(μ-S)(CO)4(dppm)2}
  参考文献：
  名称：

  Antonelli, David M.; Cowie, Martin, Inorganic Chemistry, 1990, vol. 29, # 18, p. 3339 - 3345

  摘要：

  DOI：
• 作为产物：
  描述：

  {RhRe(CO)3(μ-H)2(bis(diphenylphosphino)methane)2} 在 CO 作用下， 以 not given 为溶剂， 生成 {RhRe(CO)4(bis(diphenylphosphino)methane)2}
  参考文献：
  名称：

  Antonelli, David M.; Cowie, Martin, Inorganic Chemistry, 1990, vol. 29, # 20, p. 4039 - 4045

  摘要：

  DOI：

文献信息

• A convenient general route to a series of diphosphine-bridged heterobinuclear complexes that contain rhodium and structures of the mixed-valent complexes [RhM(CO)4(Ph2PCH2PPh2)2] (M = Mn, Re)
  作者：David M. Antonelli、Martin Cowie

  DOI：10.1021/om00156a022

  日期：1990.6
• Antonelli, David M.; Cowie, Martin, Organometallics, 1991, vol. 10, # 8, p. 2550 - 2559
  作者：Antonelli, David M.、Cowie, Martin

  DOI：——

  日期：——
• Unusual mixed-metal carbonate-bridged complexes via oxidation of a carbonyl ligand in [RhM(CO)4(Ph2PCH2PPh2)2] (M = Mn, Re) and [IrRe(CO)5(Ph2PCH2PPh2)2]
  作者：David M. Antonelli、Martin Cowie

  DOI：10.1021/om00053a020

  日期：1991.7

  The complexes [RhM(CO)4(dppm)2] (M = Mn (1), Re (2); dppm = Ph2PCH2PPh2) and [IrRe(CO)5(dppm)2] (3) react with molecular oxygen to give the corresponding carbonate complexes [RhM(CO)3(mu-CO3)(dppm)2] (M = Mn (4), Re (5)) and [IrRe(CO)3(mu-CO3)(dppm)2] (6). No intermediates were observed in these reactions even at -60-degrees-C. The X-ray structure determination of compound 4 shows that the carbonate ligand bridges the metals in a unique mu-2-eta-2 fashion in which one oxygen atom bridges the metals and another is also bound in Mn leaving one oxygen uncoordinated. Compound 4 crystallizes in the monoclinic space group C2/c with a = 35.591 (6) angstrom, b = 12.556 (3) angstrom, c = 25.277 (5) angstrom, beta = 116.46 (2)-degrees, V = 10112.8 angstrom 3, and Z = 8. The structure, which displays a 70:30 rotationally disordered ''RhMn(CO)3(mu-CO3)'' moiety, has refined to R = 0.079 and R(w) = 0.104 on the basis of 366 parameters refined and 2942 independent observations.