4,4'-bis(pentylamino)biphenyl | 78015-23-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4,4'-bis(pentylamino)biphenyl
• 英文别名: N-pentyl-4-[4-(pentylamino)phenyl]aniline
• CAS: 78015-23-3
• 化学式: C₂₂H₃₂N₂
• 分子量: 324.509
• InChiKey: FQGSMOGFXZTXPE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  24
• 可旋转键数：
  11
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  24.1
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  联苯胺 、 戊醇 在 镍 作用下， 反应 15.0h， 生成 4,4'-bis(pentylamino)biphenyl
  参考文献：
  名称：

  Weissflog, Wolfgang, Zeitschrift fur Chemie, 1981, vol. 21, # 1, p. 35 - 36

  摘要：

  DOI：

文献信息

• CHARGE-TRANSPORTING VARNISH
  申请人：Nissan Chemical Industries, Ltd.

  公开号：EP2963699A1

  公开（公告）日：2016-01-06

  A charge-transporting varnish including charge-transporting material comprising N,N'-diaryl benzidine derivatives represented by formula (1), a charge-accepting dopant comprising heteropoly acid, and an organic solvent. [In the formula, R1 to R8 independently represent hydrogen, a halogen, an alkyl having 1 to 20 carbon atoms, an alkenyl having 2 to 20 carbon atoms or an alkynyl having 2 to 20 carbon atoms; and Ar1 and Ar2 independently represent groups represented by formulas (2) or (3). (In the formula, R9 to R18 independently represent hydrogen, a halogen, an alkyl having 1 to 20 carbon atoms, an alkenyl having 2 to 20 carbon atoms or an alkynyl having 2 to 20 carbon atoms; and X1 and X2 independently represent hydrogen, a halogen, an alkyl having 1 to 20 carbon atoms, an alkenyl having 2 to 20 carbon atoms, an alkynyl having 2 to 20 carbon atoms, diphenylamino, 1-naphthylphenylamino, 2-naphthylphenylamino, di(1-naphthyl)-amino, and di(2-naphthyl)-amino or 1-naphthyl-2-naphtylamino.)]

  一种电荷传输清漆，包括由式（1）表示的 N,N'-二芳基联苯胺衍生物、由杂多酸组成的电荷接受掺杂剂和有机溶剂组成的电荷传输材料。 [式中，R1 至 R8 分别代表氢、卤素、具有 1 至 20 个碳原子的烷基、具有 2 至 20 个碳原子的烯基或具有 2 至 20 个碳原子的炔基；Ar1 和 Ar2 分别代表式 (2) 或 (3) 所代表的基团。 (在式中，R9 至 R18 独立地代表氢、卤素、具有 1 至 20 个碳原子的烷基、具有 2 至 20 个碳原子的烯基或具有 2 至 20 个碳原子的炔基；以及 X1 和 X2 独立地代表氢、卤素、具有 1 至 20 个碳原子的烷基、具有 2 至 20 个碳原子的烯基、具有 2 至 20 个碳原子的炔基、二苯基氨基、1-萘基苯基氨基、2-萘基苯基氨基、二（1-萘基）氨基和二（2-萘基）氨基或 1-萘基-2-萘基氨基。)]
• ARYLSULFONIC ACID COMPOUND, USE THEREOF, AND METHOD FOR PRODUCING ARYLSULFONIC ACID COMPOUND
  申请人：Nissan Chemical Industries, Ltd.

  公开号：EP3056484A1

  公开（公告）日：2016-08-17

  Provided is an arylsulfonic acid compound characterized by being represented by formula (1). [In the formula, Ar1 represents a group represented by formula (2) (in formula (2), R1 to R5 each independently represent a hydrogen atom, halogen atom, cyano group, nitro group, methyl group, or trifluoromethyl group; however, at least one of R1 to R5 represents a halogen atom) and Ar2 represents a group represented by formula (3) or (4).]

  本发明提供了一种芳基磺酸化合物，其特征在于由式（1）表示。 [式中，Ar1 代表由式（2）表示的基团（式（2）中，R1 至 R5 各自独立地代表氢原子、卤素原子、氰基、硝基、甲基或三氟甲基；但是，R1 至 R5 中至少有一个代表卤素原子），Ar2 代表由式（3）或（4）表示的基团。］
• ARYL SULFONIC ACID COMPOUND AND USE OF SAME
  申请人：Nissan Chemical Industries, Ltd.

  公开号：EP3101002A1

  公开（公告）日：2016-12-07

  An aryl sulfonic acid compound represented by formula (1).         Ar1-O-Ar2     (1) [In the formula, Ar1 represents a group represented by formula (2), and Ar2 represents a group represented by formula (3). (in the formula, q represents an integer of 1-4.)]

  式 (1) 所代表的芳基磺酸化合物。 Ar1-O-Ar2 (1) [式中，Ar1 代表由式（2）表示的基团，Ar2 代表由式（3）表示的基团。 (式中，q 代表 1-4 的整数）]。
• TRIARYLAMINE DERIVATIVE AND USE OF SAME
  申请人：Nissan Chemical Industries, Ltd.

  公开号：EP3124466A1

  公开（公告）日：2017-02-01

  Provided is a triarylamine derivative represented by formula (1). [In the formula, Ar1-Ar4 each independently represent a phenyl group, 1-naphthyl group, 2-naphthyl group, 1-anthryl group, 2-anthryl group, 9-anthryl group, 1-phenanthryl group, 2-phenanthryl group, 3-phenanthryl group, 4-phenanthryl group, or 9-phenanthryl group, and X represents a divalent group represented by formula (2). (In the formula, A represents a C1-C6 fluoroalkanediyl group.)]

  本发明提供了一种由式（1）表示的三芳基胺衍生物。 [式中，Ar1-Ar4 各自独立地代表苯基、1-萘基、2-萘基、1-蒽基、2-蒽基、9-蒽基、1-菲基、2-菲基、3-菲基、4-菲基或 9-菲基，X 代表式（2）所代表的二价基团。 (式中，A 代表 C1-C6 氟烷二基）]。
• CHARGE-TRANSPORTING MATERIAL
  申请人：Nissan Chemical Industries, Ltd.

  公开号：EP3174116A1

  公开（公告）日：2017-05-31

  This charge-transporting material, which includes a charge-transporting substance, halo-tetracyanoquinodimethane, and a complexing agent comprising an amide compound such as 1,3-dimethyl-2-imidazolidinone, for example, and capable of forming a complex with halo-tetracyanoquinodimethane, and in which the halo-tetracyanoquinodimethane and complexing agent form a complex, makes it possible to provide a thin film having excellent charge-transporting properties and to realize an organic EL element having low drive voltage when said thin film is applied to a hole injection layer.

  这种电荷传输材料包括电荷传输物质卤代四氰醌二甲烷和络合剂，络合剂由例如 1,3-二甲基-2-咪唑烷酮之类的酰胺化合物组成，能够与卤代四氰醌二甲烷形成络合物、以及卤代-四氰基喹啉二甲烷和络合剂形成络合物的情况下，可以提供具有优异电荷传输特性的薄膜，并在将所述薄膜应用于空穴注入层时，实现具有低驱动电压的有机电致发光元件。