trans-bis(2,4,5,6-tetraphenyl-1,3,2,5-dioxaboraphosphorinane)Pt dichloride | 138191-51-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: trans-bis(2,4,5,6-tetraphenyl-1,3,2,5-dioxaboraphosphorinane)Pt dichloride
• CAS: 138191-51-2
• 化学式: C₅₂H₄₄B₂Cl₂O₄P₂Pt
• 分子量: 1082.47
• InChiKey: RQHFFGCFGBTLPZ-JINOMOBRSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  12.64
• 重原子数：
  63.0
• 可旋转键数：
  10.0
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  36.92
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为产物：
  描述：

  2,4,5,6-tetraphenyl-1,3,2,5-dioxaboraphosphorinane 、 platinum(II) chloride 以 乙腈 为溶剂， 以61%的产率得到trans-bis(2,4,5,6-tetraphenyl-1,3,2,5-dioxaboraphosphorinane)Pt dichloride
  参考文献：
  名称：

  Synthesis and structural features of 1,3,2,5-dioxaboraphosphorinane complexes with Pt(II) and Pd(II) salts

  摘要：

  Complexes of composition L2MCl2 [M = Pt, R = H (I), Me (II), Ph (III)] and LMCl2 [M = Pd, R = H (IV)] are prepared by reaction of 4,6-R2-2,5-diphenyl-1,3,2,5-dioxaboraphosphorinanes (L) with MCl2. Far-IR and P-31 NMR spectroscopy are used to demonstrate that I is cis whereas II and III are trans complexes in the solid. The conformational behavior of I is studied by P-31 and H-1 NMR. The asymmetric form of I exhibits anomalous stability.

  DOI：

  10.1007/bf00963499