Mn(N-(o-vanillinidene)-p-anisidine)(CH3COO)(H2O) | 615252-27-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Mn(N-(o-vanillinidene)-p-anisidine)(CH3COO)(H2O)
• CAS: 615252-27-2
• 化学式: C₁₇H₁₉MnNO₆
• 分子量: 388.279
• InChiKey: SHUNIXSULDRCTL-BCSAYTTPSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-methoxy-6-(((4-methoxyphenyl)imino)methyl)phenol 、 manganese (II) acetate tetrahydrate 以 乙醇 、 N,N-二甲基甲酰胺 为溶剂， 以60%的产率得到Mn(N-(o-vanillinidene)-p-anisidine)(CH3COO)(H2O)
  参考文献：
  名称：

  Synthesis and Characterization of N‐(o‐Vanillinidene)‐p‐anisidine and N,N′‐bis(o‐Vanillinidene)ethylenediamine and Their Metal Complexes

  摘要：

  Two Schiff bases, N-(o-vanillinidene)-p-anisidine (o-VPAH) and N,N'-bis(o-vanillinidene)ethylenediamine (o-VEDH2), and eleven complexes of the compositions [M(L)(OAc)(H2O)] {where M = Cu(II) (1), Co(II) (2), Mn(II) (3) or Ni(II) (4) and OAcH = CH3COOH}, [Zn(L)(2)].H2O (5), [M(L')(H2O)(2)] {where M = Cu(II) (6) or Ni(H) (7)}, [Zn(L')].2H(2)O (8), [Sm(L')(OAc)(H2O)] (9), [Th(L')(NO3)(2)] (10) and [UO2(L')(H2O)] H2O(11)(where LH = o-VPAH, and L'H-2, = o-VEDH2), were prepared. From the elemental analyses, IR, electronic and NMR spectra, magnetic susceptibility measurements and thermal studies, the mode of chelation of the ligands and geometry of the complex molecules were assigned. In all of the complexes, o-VPAH acts as a monobasic-bidentate ligand and o-VEDH2 acts as a dibasic-tetradentate ligand. The presence of water is revealed by thermograms and supported by the presence of relevant hands in their IR spectra. Suitable structures have been proposed for these complexes.

  DOI：

  10.1081/sim-120021648