| 172665-72-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 172665-72-4
• 化学式: C₂₉H₂₄N₂O₂S₂*Ni
• 分子量: 555.344
• InChiKey: AOKWKDROOSOFSQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  nickel(II) chloride hexahydrate 、 1,3-di(o-salicylaldiminophenylthio)propane 在 NH₃ 作用下， 以 甲醇 、 氯仿 为溶剂， 以75%的产率得到
  参考文献：
  名称：

  Complexes of hexadentate nso donor ligands-III. Nickel(II) complexes of 1,3-di(o-salicylaldiminophenylthio)propane and 1,2-di(o-salicylaldiminophenylthio)xylene

  摘要：

  Nickel(II) complexes of the hexadentate N2S2O2 donor ligands, 1,3-di(o-salicylaldiminophenylthio)propane (H(2)DSALPTP) and 1,2-di(o-salicylaldiminophenylthio)xylene (H(2)DSALPTX) have been synthesised and characterised. H(2)DSALPTP reacted with NiCl2.6H(2)O or Ni(ClO4)(2).6H(2)O in presence of ammonia to give the complex [Ni(DSALPTP)] (1). H(2)DSALPTX reacted smoothly with N(ClO4)(2) to yield the corresponding complex [Ni(DSALPTX)] (2). The ligand did not react with NiCl2 in the absence of ammonia but in its presence produced the complex (2). The molecular and crystal structure;of [Ni(DSAL PTX)] exhibits a very unusual deployment of the six donor sites of the ligand. It crystallises in the orthorhombic system with space group P2(1)2(1)2(1). In dichloromethane solution both the complexes are found to exhibit Ni(II)/Ni(III) redox couples in their cyclic voltammograms at room temperature with E-1/2 values 0.87 and 0.78 V (vs. Ag/AgCl). (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00127-2

文献信息

• Synthesis, spectroscopic and redox behaviour of copper(II), nickel(II) and cobalt(II) complexes of some macrocyclic multidentates
  作者：PR. Athappan、G. Rajagopal

  DOI：10.1016/0277-5387(95)00182-r

  日期：1996.2

  Copper(II) complexes of neutral tetradentate diamines and a series of copper(II), nickel(II) and cobalt(II) complexes of a new class of dibasic hexadentate Schiff bases, derived from the above diamines and salicylaldehyde or 2-hydroxy-1-naphthaldehyde, have been prepared and characterized by elemental analysis, magnetic susceptibility and IR and electronic spectral studies. The electrochemical behaviour

  中性四齿二胺的铜（II）配合物，以及由上述二胺和水杨醛或2-羟基-苯胺衍生的新型二元六齿席夫碱的一系列铜（II），镍（II）和钴（II）配合物已经制备了1-萘醛，并通过元素分析，磁化率以及红外光谱和电子光谱研究对其进行了表征。还研究了铜（II）和钴（II）配合物的电化学行为以及所有铜（II）配合物的ESR光谱参数。配体场强随螯合物环尺寸从六增加到七而增加。ESR光谱数据表明，铜（II）配合物呈现单体扭曲的八面体或拟四面体结构。乙腈中的II / Cu I和Co II / Co I对。