| 574704-41-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 574704-41-9
• 化学式: C₃₂H₃₂CoN₄O₄S₂*H₂O
• 分子量: 677.771
• InChiKey: LYHNURQHDMSKGE-DCMYMFDXSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N,N'-bis(2-tosylaminobenzylidene)-1,4-diaminobutane 、 水 、 钴 在 NMe₄ClO₄ 作用下， 以 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Metallo-helicates with an N4-Schiff base containing a flexible alkyl spacer

  摘要：

  Neutral Mn(II), Fe(II) and Co(II) complexes with an N-tosyl substituted N-4-Schiff base containing a tetra-methylene spacer have been prepared. The X-ray crystal structures of ligand H2BTs [N,N-bis(2-tosylaminobenzylidene)-1,4-diaminobutane] and helical Co(BTs)(.)0.5H(2)BTs have been solved. The Co(II) ion assumes a distorted tetrahedral coordination geometry, involving the four donor N-atoms of the dianionic ligand. Additionally, secondary interactions between the metal centre and one of the O-atoms of each tosyl group were detected. These groups are differently conformed, so that the ligand behaves as a non-symmetric helicand. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)01441-x