[Ni(1-(4,6-dimethyl-pyrimidin-2-ylazo)-naphthalen-2-ol(1-))2(EtOH)2]H2O | 871584-39-3

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: [Ni(1-(4,6-dimethyl-pyrimidin-2-ylazo)-naphthalen-2-ol(1-))2(EtOH)2]H2O
• CAS: 871584-39-3
• 化学式: C₃₆H₃₈N₈NiO₄*H₂O
• 分子量: 723.454
• InChiKey: PRVYQDACKSRMGX-ZEXGZYBBSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Ni(1-(4,6-dimethyl-pyrimidin-2-ylazo)-naphthalen-2-ol(1-))2(EtOH)2]H2O 以 neat (no solvent, solid phase) 为溶剂， 生成 nickel(II) oxide
  参考文献：
  名称：

  Synthesis, spectral and thermal studies of Co(II), Ni(II) and Cu(II) complexes 1-(4,6-dimethyl-pyrimidin-2-ylazo)-naphthalen-2-ol

  摘要：

  The electronic absorption spectra of]-(4,6-dimethyl-pyrimidin-2-ylazo)-naphthalen-2-ol is studied in organic solvents of different polarity as well as in buffer solutions of varying pH values at different temperatures and different ratios of methanol. The probable structure of the azodye has been assigned on the basis of spectral studies (IR and H-1 NMR). The effect of Co(11), Ni(11) and Cu(11) ions on the emission spectrum of the free azodye is also assigned. The stoichiometry of the metal complexes is determined spectrophotometrically and conductometrically. Novel complexes of Co(11), Ni(11) and Cu(11) with the pyrimidine azodye have been synthesized and characterized on the basis of elemental analyses, molar conductance, magnetic susceptibility measurements, IR, electronic as well as ESR spectral studies The thermal decomposition of the metal complexes is studied by TGA and DTA techniques. The kinetic parameters like activation energy, pre-exponential factor and entropy of activation are estimated. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2005.02.039
• 作为产物：
  描述：

  乙醇 、 1-(4,6-dimethyl-pyrimidin-2-ylazo)-naphthalen-2-ol 、 nickel diacetate 以 乙醇 为溶剂， 生成 [Ni(1-(4,6-dimethyl-pyrimidin-2-ylazo)-naphthalen-2-ol(1-))2(EtOH)2]H2O
  参考文献：
  名称：

  Synthesis, spectral and thermal studies of Co(II), Ni(II) and Cu(II) complexes 1-(4,6-dimethyl-pyrimidin-2-ylazo)-naphthalen-2-ol

  摘要：

  The electronic absorption spectra of]-(4,6-dimethyl-pyrimidin-2-ylazo)-naphthalen-2-ol is studied in organic solvents of different polarity as well as in buffer solutions of varying pH values at different temperatures and different ratios of methanol. The probable structure of the azodye has been assigned on the basis of spectral studies (IR and H-1 NMR). The effect of Co(11), Ni(11) and Cu(11) ions on the emission spectrum of the free azodye is also assigned. The stoichiometry of the metal complexes is determined spectrophotometrically and conductometrically. Novel complexes of Co(11), Ni(11) and Cu(11) with the pyrimidine azodye have been synthesized and characterized on the basis of elemental analyses, molar conductance, magnetic susceptibility measurements, IR, electronic as well as ESR spectral studies The thermal decomposition of the metal complexes is studied by TGA and DTA techniques. The kinetic parameters like activation energy, pre-exponential factor and entropy of activation are estimated. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2005.02.039