| 66969-07-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• CAS: 66969-07-1；18040-72-7
• 化学式: C₁₆H₁₂F₆O₈S₂U
• 分子量: 748.418
• InChiKey: VTYLQCQIQQIXQV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  苯并-15-冠醚-5 、 以 氯仿 为溶剂， 以85%的产率得到[UO2(thenoyl trifluoroacetonato)2H2O]2(benzo-15-crown-5)
  参考文献：
  名称：

  Crown ether compounds of actinide bis(β-diketonate). Synthesis, characterization and molecular structures of [UO2(TTA)2H2O]2(benzo-15,crown-5) (1) and [UO2(TTA)2(μ-H2O)]2(H2O)2(dibenzo-18,crown-6) (2)

  摘要：

  Reaction of [UO2(TTA)(2)2H(2)O] with benzo-15,crown-5 in chloroform yielded the compound [UO2(TTA)(2)H2O](2)(benzo-15,crown-5) (1) in which the benzo-15,crown-5 ether acts as a second sphere ligand. However, similar reaction with dibenzo-18,crown-6 yielded the compound [UO2(TTA)(2)(mu -H2O)](2)(H2O)(2)(dibenzo-18,crown-6) (2) in which the dibenzo-18,crown-6 ether acts as a third sphere ligand. The solid state structure of I shows that the crown ether bridges two mononuclear [UO2(TTA)(2)H2O] by hydrogen bonds to give binuclear complex [UO2(TTA)(2)H2O](2)crown. Two of such binuclear units are stabilized by C-(HO)-O-... interactions in the solid state. The structure of 2 shows that the crown ether bridges two binuclear [UO2(TTA)(2)(mu -H2O)](2)(H2O)(2) by hydrogen bonds along the c-axis direction to give linear polymeric chain-like arrangement. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(01)00815-4