2-propyl-5,10,15,20-tetraphenylporphyrinatocopper | 1257343-17-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: 2-propyl-5,10,15,20-tetraphenylporphyrinatocopper
• CAS: 1257343-17-1
• 化学式: C₄₇H₃₄CuN₄
• 分子量: 718.36
• InChiKey: HBNLVHXLVSFQGG-GBGVRRJWSA-N

反应信息

• 作为产物：
  描述：

  2-(2-formylvinyl)-5,10,15,20-tetraphenylporphyrinatocopper 在 甲酸 、 5% Pd(II)/C(eggshell) 作用下， 以 1,4-二氧六环 为溶剂， 反应 3.0h， 以77%的产率得到2-propyl-5,10,15,20-tetraphenylporphyrinatocopper
  参考文献：
  名称：

  Porphyrins and their derivatives: XXVI. Synthesis and properties of 2-(3-butenyl)-5,10,15,20-tetraphenylporphyrin

  摘要：

  2-[2-(1,3-Dioxolan-2-yl)vinyl]-5,10,15,20-tetraphenylporphyrin and its copper complex were reduced into the corresponding ethyldioxolanes by diimide generated in the system hydrazine hydrate - air oxygen - pyridine. The hydrolysis of the obtained ethyldioxolanes results in the formylethyl derivatives that react with the methylenetriphenylphosphorane to form 2-(3-butenyl)-5,10,15,20-tetraphenyl porphyrin and its copper complex.

  DOI：

  10.1134/s1070428010090241