bis{N,N'(dithiobis(ethylene)(salicylideneiminato))}zinc(II) | 139941-66-5

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: bis{N,N'(dithiobis(ethylene)(salicylideneiminato))}zinc(II)
• 英文别名: zinc;2-[2-[2-[(2-oxidophenyl)methylideneamino]ethyldisulfanyl]ethyliminomethyl]phenolate
• CAS: 139941-66-5
• 化学式: C₁₈H₁₈N₂O₂S₂Zn
• 分子量: 423.875
• InChiKey: RDVOLHGOIKIRQL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,2'-bisphenol 、 锌 以 甲醇 为溶剂， 生成 bis{N,N'(dithiobis(ethylene)(salicylideneiminato))}zinc(II)
  参考文献：
  名称：

  Electrochemical synthesis, structure, magnetic and tribochemical properties of metallochelates of new azomethine ligands, bis-[2-(N-tosylaminobenzylidenealkyl(aryl)]disulfides

  摘要：

  On the basis of new ligand systems, bis-azomethines of N-tosylaminobenzaldehyde and alkyl(aryl)diaminodisulfides, mono- and binuclear chelates with 4N- and 2N2S-ligand arrangement were chemically (from metal acetates) or electrochemically (from metals in the zero oxidation state) first synthesized and characterized. Mononuclear chelates have a tetrahedral structure. In binuclear copper complexes the magnetic exchange interaction of the antiferromagnetic type was observed. Bisazomethines of disulfides were used as additives to lubricant oils.

  DOI：

  10.1134/s1070363209030128

文献信息

• The electrochemical synthesis of zinc(II) complexes of 2-(2-mercaptophenyl)-imino-phenols and the crystal structure of bis{N,N′[dithiobis(ethylene)](4,6-dimethoxysalicylideneiminato)}zinc(II)
  作者：Elena Labisbal、Jaime Romero、Andres de Blas、José A. García-Vázquez、María L. Duran、Alfonso Castiñeiras、Antonio Sousa、David E. Fenton

  DOI：10.1016/s0277-5387(00)83259-3

  日期：1992.1

  The electrochemical oxidation of anodic zinc in acetonitrile solutions of the Schiff bases derived from the required salicylaldehyde and bis-(2-aminophenyl)disulphide (L2H2) yields compounds of formula ZnL2. The crystal structure of bisN,N'[dithio-bis(ethylene)](4,6-dimethoxysalicylideneiminato)}zinc(II) [Zn(L(2)1)] has been determined. The zinc atom has a distorted tetrahedral coordination geometry derived from the iminonitrogen and phenoxy-oxygen donor atoms.