| 140889-82-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 140889-82-3
• 化学式: C₃₀H₃₅AsO₃P₂Pt
• 分子量: 775.555
• InChiKey: YMVALSMDSKUMIJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  37.0
• 可旋转键数：
  9.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  35.53
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为产物：
  描述：

  三苯胂 、 苯膦酸 、 trans-[Pt(PEt₃)Br(μ-Br)]₂ 在 Ag₂O 作用下， 以 二氯甲烷 为溶剂， 以98%的产率得到
  参考文献：
  名称：

  Synthesis and reactivity of phosphonato, phosphato and arsonato complexes of platinum(II)

  摘要：

  Treatment of the complexes cis-[PtCl2L2] (L = donor ligand) with phenylphosphonic acid, methylphosphonic acid, phenyl dihydrogenphosphate or phenylarsonic acid in the presence of an excess of silver(I) oxide in refluxing dichloromethane yielded the new metallacyles [activated Pt{OP(O)(Ph)O}L2], [activated Pt{OP(O)(Me)O}L2], [activated Pt{OP(O)(OPh)O}L2] or [activated Pt{OAs(O)(Ph)O}L2] respectively. The X-ray crystal structure of [activated Pt{OP(O)(Ph)O}(PMePh2)2] showed the presence of a slightly puckered metallacyclic ring with the phosphoryl oxygen adopting an equatorial position. A decomposition product of the complex [activated Pt{OP(O)(Ph)O}{P(CH2Ph)Ph2}2] in solution was shown, via an X-ray crystal structure determination, to be the diorthometallated complex cis-[activated Pt(C6H4CH2PPh2)2].

  DOI：

  10.1039/dt9920000851