{(2,2'-bipyrimidine)Ru(4,4',5,5'-tetramethyl-2,2'-bipyridine)2}(2+) | 165881-97-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: {(2,2'-bipyrimidine)Ru(4,4',5,5'-tetramethyl-2,2'-bipyridine)2}(2+)
• 英文别名: bis(4,4',5,5'-tetramethyl-2,2'-bipyridine)(2,2'-bipyrimidine)ruthenium(II)(2+)
• CAS: 165881-97-0
• 化学式: C₃₆H₃₈N₈Ru
• 分子量: 683.821
• InChiKey: KEKTYQQITSMWPL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  {(2,2'-bipyrimidine)Ru(4,4',5,5'-tetramethyl-2,2'-bipyridine)2}(2+) 在 sodium (-)-O,O'-dibenzoyl-L-tartrate 作用下， 以 水 为溶剂， 生成 Δ-(-)-[Ru(4,4',5,5'-tetramethyl-2,2'-bipyridine)2(2,2'-bipyrimidine)](PF6)2 、 Δ-(-)-[Ru(4,4',5,5'-tetramethyl-2,2'-bipyridine)2(2,2'-bipyrimidine)](PF6)2
  参考文献：
  名称：

  Chiral [Ru(pp)2(CO)2]2+ Species (pp = Bidentate Polypyridyl Ligand) and Their Use in the Stereoselective Synthesis of Ligand-Bridge Dinuclear Complexes

  摘要：

  The decarbonylation of chiral [Ru(pp)(2)(CO)(2)](2+) (pp = bidentate polypyridyl ligands) in the presence of excess pp shows stereoretention in the [Ru(pp)(3)](2+) product, and under the same conditions, its reaction with chiral [Ru(pp')(2)(BL)](2+) centers (pp and pp' may or may not be identical; BL = bridging ligand) allows synthesis of specific diastereoisomeric forms of the dinuclear species [(pp)(2)Ru(BL)Ru(pp')(2)](4+).

  DOI：

  10.1021/ic00119a004

文献信息

• Diastereoisomeric forms of ligand-bridged dimetallic diruthenium(<scp>II</scp>) and ruthenium(<scp>II</scp>)–osmium(<scp>II</scp>) species containing bidentate polypyridyl ligands
  作者：David A. Reitsma、F. Richard Keene

  DOI：10.1039/dt9930002859

  日期：——

  A new general synthetic route is reported for dinuclear species of the type [(L(t))2RuL(b)Ru(L)'2]4+ or [(L(t))2RuL(b)Os(L(t)')2]4+ (L(t), L(t)' = bidentate polypyridyl ligands, L(t), not-equal L(t)'; L(b) = bridging ligand), together with the chromatographic separation and characterization of the diastereoisomeric pairs of the dimers.