(7,16-diethyldibenzo[b,i][1,4,8,11]tetraazacyclotetradecinato)palladium(II) | 186396-10-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氮杂萘
• 英文名称: (7,16-diethyldibenzo[b,i][1,4,8,11]tetraazacyclotetradecinato)palladium(II)
• CAS: 186396-10-1
• 化学式: C₂₂H₂₂N₄Pd
• 分子量: 448.863
• InChiKey: FDRGZYNZVFPOHK-AZSHNCKFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  5,14-Dihydro-7,16-diethyldibenzo<1,4,8,11>tetraazacyclotetradecine 在 palladium(II) sodium chloride 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以41%的产率得到(7,16-diethyldibenzo[b,i][1,4,8,11]tetraazacyclotetradecinato)palladium(II)
  参考文献：
  名称：

  Preparation and characterization of zinc(II) and palladium(II) complexes with 16-ethyl-5,6,7,8,9,14-hexahydrodibenzo[b,i][1,4,8,11]-tetraazacyclotetradecine

  摘要：

  The zinc(II) and palladium(II) complexes of 16-ethyl-5,6,7,8,9,14-hexahydrodibenzo [b,i][1,4,8,11] tetraazacyclotetradecine (HL(1)) and 5,14-dihydro-7,16-diethyldibenzo[b,i] [1,4,8,11]tetraazacyclotetradecine (H(2)L(2)) have been synthesized and their spectroscopic data determined. The absorption bands of ML(1)X (M = Zn,Pd; X = Cl, NCS, ClO4) observed in the 20,400-23,900 cm(-1) region were attributable to pi-pi* and charge transfer transitions. Those bands for the three palladium(II) complexes (PdL(1)X) are similar to each other in various solvents, but the bands of ZnL(1)X are slightly different from one another. The C-13 NMR signals for NiL(1)(ClO4) and PdL(1)(ClO4) are similar to each other, but the C(15) and C(17) carbon signals for ZnL(1)(ClO4) exhibit downfield shifts upon metal coordination. Judging from the molar conductances for the complexes, ZnL(1)(ClO4) and PdL(1)X (X = Cl, NCS, ClO4) are 1:1 electrolytes in acetonitrile and nitromethane, but ZnL(1)Cl and ZnL(1) (NCS) are non-electrolytes. The treatment of PdL(1)X (X=Cl, NCS, ClO4) in methanol solution with an excess of base in air gave (7-ethyldibenzo[b,i][1,4,8,11]tetraazacyclotetradecinato)palladium(II) (PdL(3)). Copyright (C) 1996 Elsevier Science Ltd

  DOI：

  10.1016/s0277-5387(96)00342-7