Fe(pip-dtc)2(oxine) | 135986-23-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻唑类
• 英文名称: Fe(pip-dtc)2(oxine)
• CAS: 135986-23-1
• 化学式: C₂₁H₂₆FeN₃OS₄
• 分子量: 520.568
• InChiKey: SQGGIBPENQLVFV-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  8-羟基喹啉 、 三氯化铁 、 sodium piperidinedithiocarbamate 在 sodium acetate 作用下， 以 乙醇 为溶剂， 生成 Fe(pip-dtc)2(oxine)
  参考文献：
  名称：

  Mixed ugand complexes of iron(III) derived from its dithiocarbamato complexes

  摘要：

  Three different types of iron(III) complexes, Fe(A)3, Fe(A)2(A') and Fe(A)(A')2, where A is either piperidyldithiocarbamate or morpholyl dithiocarbamate and A' is glycine(oxine) acetylacetone have been prepared by reacting Fe(III) salt with sodium salt of piperidinedithiocarbamic acid or morpholine-dithiocarbamic acid and acetylacetone(oxine)-glycine in different ratios. The mixed ligand complexes have been characterised by elemental analysis, magnetic susceptibility measurements, infrared, electronic spectral techniques and by thermal analysis. Electronic spectral studies suggests that all the complexes possess distorted octahedral geometry. The magnetic moment of the high spin iron(III) complexes lies in the range of 5.88-6.00 and for low spin lies in the range of 3.36-4.34 B.M. TG studies show one step decomposition of complexes and formation of Fe2O3 at the end of the step.

  DOI：

  10.1007/bf01913654