1-((decylimino)methyl)naphthalen-2-ol | 50360-05-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1-((decylimino)methyl)naphthalen-2-ol
• 英文别名: 1-(Decyliminomethyl)naphthalen-2-ol；1-(decyliminomethyl)naphthalen-2-ol
• CAS: 50360-05-9
• 化学式: C₂₁H₂₉NO
• 分子量: 311.467
• InChiKey: ZPROUSTXWYINLI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  23
• 可旋转键数：
  10
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.48
• 拓扑面积：
  32.6
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  potassium permanganate 、 1-((decylimino)methyl)naphthalen-2-ol 以 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Structures and properties of di-μ-oxo dimanganese(IV) complexes with bidentate Schiff bases, N-alkyl-substituted-salicylideneamine

  摘要：

  Novel di-mu-oxo dimanganese(IV) complexes, [Mn-IV(N-R-X-sal)(2)(mu-O)](2), with bidentate Schiff base ligands, N-alkyl-substituted-salicylideneamine, N-R-X-salH [R= CH3(Me), C2H5 (Et), n-C3H, (Pr), n-C4H9 (Bu), n-C6H13 (Hx), n-C8H17 (Oct), II-C10H21 (Dec), n-C12H25 (Dod), or n-C18H37 (Octd) and X = H or 5,6-benzo]: have been prepared by their reaction with potassium permanganate (KMnO4) in MeCN, while stirring at room temperature. These complexes were characterized by spectroscopy, magnetic susceptibility, thermal analysis and X-ray crystallography. The structures consist of a Mn-2(IV)(mu-O)(2) core with a Mn-Mn separation of 2.731 (4) Angstrom for [Mn-IV(N-Me-sal)(2)(mu-O)](2), 1, 2.769(2) Angstrom for [Mn-2(IV)(N-Et-sal)(2)(mu-O)](2), 2, 2.780(2) Angstrom for [(Mn-IV-Hx-sal)(2)(mu-O)](2), 5, 2.780(2)Angstrom for [Mn-IV(N-Dec-sal)(2)(mu-O)](2), 7, and 2.756(3) Angstrom for [Mn-IV(N-Me-5,6-benzo-sal)(2)(mu-O)](2), 10. The complex 1 is the first di-mu-oxo dimanganese(IV) complex having asymmetrical form in which two manganese ions adopt different configurations each other. Moreover, the complexes 5 and 7 are found to exhibit the longest one among all of the Mn-Mn separation observed for the structurally characterized Mn-2(mu-O)(2) complexes prior to this work. The antiferromagnetic exchange interaction has been found to be J= -83 and -188 cm(-1) for 1 and 7, respectively. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00144-2
• 作为产物：
  描述：

  1-氨基癸烷 、 2-羟基-1-萘甲醛 以 乙醇 为溶剂， 反应 1.0h， 生成 1-((decylimino)methyl)naphthalen-2-ol
  参考文献：
  名称：

  Pudovik 反应：合成具有长烷基链的生物活性 α-氨基膦酸酯

  摘要：

  摘要 在这项研究中，我们研究了取代萘醛与胺的反应。do-、tetra-、hexa-、octadecan-1-胺与2-羟基-1-萘醛的缩合以良好的产率产生了一系列偶氮甲碱。这些化合物与双十二烷基氧化膦的后续反应产生了 α-氨基膦酸酯。合成的磷化合物对革兰氏阳性菌、革兰氏阴性菌和酵母白色念珠菌的体外微生物活性与标准试剂进行比较。合成的化合物对人和动物病原微生物菌群表现出很高的抗菌和抗真菌活性。每个新合成的化合物都通过元素分析、IR、1H NMR、31P NMR 光谱研究进行表征。通过同步热重法和差示扫描量热法(TG/DSC)研究热稳定性。图形概要

  DOI：

  10.1080/10426507.2018.1539848

文献信息

• Novel 2-(hydroxy)-naphthyl imino functionalized pillar[5]arene: a highly efficient supramolecular sensor for tandem fluorescence detection of Fe³⁺ and F⁻ and the facile separation of Fe³⁺
  作者：Wei Zhu、Hu Fang、Jun-Xia He、Wen-Hua Jia、Hong Yao、Tai-Bao Wei、Qi Lin、You-Ming Zhang

  DOI：10.1039/c8nj01335g

  日期：——

  “turn-on” fluorescence on sensing F− (LOD = 1.34 × 10−7 M). In addition, the sensor AP5N could separate Fe3+ from aqueous solution with excellent ingestion capacity, and the Fe3+ separation rate was up to 98.25%. Moreover, the fluorescence changes of AP5N upon addition of Fe3+ and F− could be utilized as an IMPLICATION logic gate. Furthermore, as a practical application, ion test strips based on AP5N

  基于2-（羟基）-萘基亚氨基亚氨基官能化柱[5]芳烃（AP5N）的高效超分子传感器，用于串联荧光检测H 2 O / DMSO中的Fe 3+和F- （1 /9，v / v）溶液已成功合成。向AP5N中添加Fe 3+后，蓝色荧光被淬灭。Fe 3+的荧光检出限估计为1.21×10 -7 M，且检测时间短。此外，AP5N -Fe 3+络合物可以选择性地显示出“接通”荧光上感测˚F -（LOD = 1.34×10 -7M）。另外，传感器AP5N能够以极好的吸收能力从水溶液中分离出Fe 3+，并且Fe 3+的分离率高达98.25％。此外，的荧光变化AP5N在加入的Fe 3+和F -可被用作一个涵义逻辑门。另外，作为实际应用中，基于离子测试条AP5N被制造，其可作为方便和有效的检验试剂盒充当用于检测的Fe 3+和F - 。
• Structures and properties of di-μ-oxo dimanganese(IV) complexes with bidentate Schiff bases, N-alkyl-substituted-salicylideneamine
  作者：Hitoshi Torayama、Hideyuki Asada、Manabu Fujiwara、Takayuki Matsushita

  DOI：10.1016/s0277-5387(98)00144-2

  日期：1998.11

  Novel di-mu-oxo dimanganese(IV) complexes, [Mn-IV(N-R-X-sal)(2)(mu-O)](2), with bidentate Schiff base ligands, N-alkyl-substituted-salicylideneamine, N-R-X-salH [R= CH3(Me), C2H5 (Et), n-C3H, (Pr), n-C4H9 (Bu), n-C6H13 (Hx), n-C8H17 (Oct), II-C10H21 (Dec), n-C12H25 (Dod), or n-C18H37 (Octd) and X = H or 5,6-benzo]: have been prepared by their reaction with potassium permanganate (KMnO4) in MeCN, while stirring at room temperature. These complexes were characterized by spectroscopy, magnetic susceptibility, thermal analysis and X-ray crystallography. The structures consist of a Mn-2(IV)(mu-O)(2) core with a Mn-Mn separation of 2.731 (4) Angstrom for [Mn-IV(N-Me-sal)(2)(mu-O)](2), 1, 2.769(2) Angstrom for [Mn-2(IV)(N-Et-sal)(2)(mu-O)](2), 2, 2.780(2) Angstrom for [(Mn-IV-Hx-sal)(2)(mu-O)](2), 5, 2.780(2)Angstrom for [Mn-IV(N-Dec-sal)(2)(mu-O)](2), 7, and 2.756(3) Angstrom for [Mn-IV(N-Me-5,6-benzo-sal)(2)(mu-O)](2), 10. The complex 1 is the first di-mu-oxo dimanganese(IV) complex having asymmetrical form in which two manganese ions adopt different configurations each other. Moreover, the complexes 5 and 7 are found to exhibit the longest one among all of the Mn-Mn separation observed for the structurally characterized Mn-2(mu-O)(2) complexes prior to this work. The antiferromagnetic exchange interaction has been found to be J= -83 and -188 cm(-1) for 1 and 7, respectively. (C) 1998 Elsevier Science Ltd. All rights reserved.
• The Pudovik reaction: the synthesis of bioactive α-aminophosphonates with long alkyl chains
  作者：Irina V. Galkina、Khasan R. Khayarov、Rustam R. Davletshin、Aynaz Z. Gaynullin、Alexander V. Gerasimov、Marina P. Shulaeva、Oskar K. Pozdeev、Svetlana N. Egorova、Luiza M. Usupova、Vladimir I. Galkin

  DOI：10.1080/10426507.2018.1539848

  日期：2019.5.27

  Abstract In this research we investigated the reactions of substituted naphthaldehyde with amines. The condensation of do-, tetra-, hexa-, octadecan-1-amines with 2-hydroxy-1-naphthaldehyde yielded a series of azomethines in good yields. Subsequent reaction of these compounds with didodecylphosphine oxide yielded α-aminophosphonates. The in vitro microbiological activity of the synthesized phosphorus

  摘要 在这项研究中，我们研究了取代萘醛与胺的反应。do-、tetra-、hexa-、octadecan-1-胺与2-羟基-1-萘醛的缩合以良好的产率产生了一系列偶氮甲碱。这些化合物与双十二烷基氧化膦的后续反应产生了 α-氨基膦酸酯。合成的磷化合物对革兰氏阳性菌、革兰氏阴性菌和酵母白色念珠菌的体外微生物活性与标准试剂进行比较。合成的化合物对人和动物病原微生物菌群表现出很高的抗菌和抗真菌活性。每个新合成的化合物都通过元素分析、IR、1H NMR、31P NMR 光谱研究进行表征。通过同步热重法和差示扫描量热法(TG/DSC)研究热稳定性。图形概要